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Copper(II) complexes of 4-acetamidobenzaldehyde N(4)-substituted thiosemicarbazones

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Abstract

Mononuclear and binuclear copper(II) complexes with four 4-acetamidobenzaldehyde N(4)-substituted thiosemicarbazones have been prepared in EtOH solution and characterized by physical and spectral methods. I.r., electronic, and e.s.r. spectra of the complexes, as well as i.r., electronic, and n.m.r. spectra of the thiosemicarbazones, have been obtained. These thiosemicarbazones coordinate as anionic or neutral ligands via the thiosemicarbazone moiety's imine nitrogen and thiolate/thione sulfur, the former on loss of the hydrazido hydrogen, N(2)H.

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Authors and Affiliations

  1. Department of Chemistry, Illinois State University, Normal, IL, 61790-4160, USA

    Douglas X. West, Heloisa Beraldo & Amal A. Nassar

  2. Department of Chemistry, El-Menoufia University, Shebin, El-Kom, Egypt

    Fathy A. El-Saied & Mohammed I. Ayad

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  1. Douglas X. West
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  2. Heloisa Beraldo
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  3. Amal A. Nassar
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  4. Fathy A. El-Saied
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  5. Mohammed I. Ayad
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West, D.X., Beraldo, H., Nassar, A.A. et al. Copper(II) complexes of 4-acetamidobenzaldehyde N(4)-substituted thiosemicarbazones. Transition Metal Chemistry 24, 421–424 (1999). https://doi.org/10.1023/A:1006967802158

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