Abstract
Two novel telluroether-disubstituted metal carbonyls, [(R2Te)M(CO)4]2(M = Mn or Re; R = p-MeOC6H4), were prepared from [M2(CO)10] by an oxygen atom transfer. The axial CO is replaced by the telluroether when [M2(CO)10] reacts with a new kind of oxygen transfer reagent, R2TeO, under mild conditions. The products were characterized by elemental analysis, i.r., 1H- and 13C-n.m.r., and FAB-mass spectra. The configuration of the substituted carbonyl is unique, i.e. the 1, l′-diax isomer.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
U. Koelle, J. Organometal. Chem., 155, 53 (1978).
D.J. Cox and R. Davis, J. Organometal. Chem., 186, 339 (1980).
E. Singleton, J.T. Moelwyn-Hughes and A.W.B. Garner, J. Orgnometal. Chem., 21, 449 (1970).
J.T. Moelwyn-Hughes, A.W.B. Carner and N. Gordon, J. Orgno-metal. Chem., 26, 373 (1971).
S.W. Lee, L.F. Wang and C.P. Cheng, J. Organometal. Chem., 248, 189 (1983).
P.O. Nubel and T.L. Brown, J. Am. Chem. Soc., 106, 644 (1984).
H. Wawersik and F. Basolo, Inorg. Chim. Acta, 3, 113 (1969).
W. Hieber and W. Freyer, Chem. Ber., 92, 1765 (1959).
D.G. Dewit, J.P. Fawcett and A. PoeÈ, J. Chem. Soc'. Dalton Trans., 528 (1976).
L.K. Peterson, R.S. Dhami and F. Wade, Synth. React. Inorg. Met-org. Chem., 13, 291 (1983).
J.D. Atwood and T.C. Brown, J. Am. Chem. Soc., 98, 3160 (1976).
G.W. Harris and N.J. Coville, Organometallics, 4, 908 (1985).
D.J. Robinson, G.W. Harris, J.C.A. Boeyens and N.J. Coville, J. Chem. Soc. Chem. Comm., 1307 (1984).
H. Wawersik and F. Basolo, J. Chem. Soc. Chem. Comm., 366 (1996)
N. Petragnani and J.V. Comasseto, Synthesis, 1 (1986).
J.K. Shen., Y.C. Gao, Q.Z. Shi, A.L. Rheingold and F. Bosolo, Inorg. Chem., 30, 1868 (1991).
Y.C. Gao, J.K. Shen, L. Peng, Q.Z. Shi and F. Bosolo, J. Indian Chem. Soc., 69, 464 (1992).
Y.C. Gao, X.J. Yang and Q.Z. Shi, Inorg. Chim. Acta, 240, 661 (1995).
M. Xue, Y.C. Gao, J.K. Shen, Q.Z. Shi and F. Bosolo, Inorg Chim. Acta, 207, 207 (1993).
S.V. Ley and C.A. Meerholz, Tetrahedron, 37, 213 (1981).
A.G. Osborne and M.H.B. Stiddard, J. Chem. Soc., 634 (1964).
M.Y. Darensbourg, H.L. Condor, D.J. Darensbourg and C. Hasday, J. Am. Chem. Soc., 95, 5919 (1973).
Y.C. Gao, Q.Z. Shi, D.L. Kershner and F. Basolo, Inorg. Chem., 27, 188 (1988).
W.F. Fiaw, M.H. Chiang, C.H. Lai, S.J. Chiou, G.H. Lee and S.M. Peng, Inorg. Chem., 33, 2493 (1994).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Liu, X., Gao, YC., Su, ZX. et al. Substituted metal carbonyls: [{{(p-MeOC6H4)2Te}M(CO)4}]2 (M = Mn or Re) in the presence of an O-atom transfer reagent. Transition Metal Chemistry 24, 666–668 (1999). https://doi.org/10.1023/A:1006988103269
Issue Date:
DOI: https://doi.org/10.1023/A:1006988103269