Summary
The electrochemical behaviour of a series of mononuclear and dinuclear complexes of dioxouranium(VI), nickel(II) and copper(II) ions with the Schiff base, H4fsalacen, derived from the condensation of 3-formylsalicylic acid and 1,2-diaminoethane, is reported.
The potentially hexadentate compartmental ligand H4fsalacen has an outer O2O2 and an inner N2O2 coordination site. The redox properties of the metal ions in these two different and adjacent chambers have been investigated and compared with those of the analogous complexes with the ligand H4 aapen, obtained by reaction ofo-acetoacetylphenol and 1,2-diaminoethane.
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Zanello, P., Tamburini, S., Vigato, P.A. et al. Electrochemistry of transition metal complexes of Schiff base compartmental ligands. Transition Met Chem 9, 176–180 (1984). https://doi.org/10.1007/BF00618611
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DOI: https://doi.org/10.1007/BF00618611