Abstract
Mono- and disubstitution of HCo(CO)4 with tertiary phosphines and phosphites was studied by IR and1H-NMR spectroscopy. It was found that these substitutions proceed through phosphonium tetracarbonylcobaltate intermediates, leading to a mixture of isomers. The crystal and molecular structure of trans-HCo(CO)3[P(O-p-C6H4Ph)3] was determined by X-ray diffraction.
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GDR research fellow at the University of Veszprém.
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Bartik, T., Krümmung, T., Happ, B. et al. Intermediates and isomers in the substitution of cobalt carbonyl hydride with tertiary phosphorous ligands. Catal Lett 19, 383–389 (1993). https://doi.org/10.1007/BF00767082
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DOI: https://doi.org/10.1007/BF00767082