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Temporal and spatial self-organisation in catalysis at single crystal surfaces

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Abstract

The elementary steps underlying the mechanism of a catalytic reaction are also responsible for its rate under steady-state conditions. In special cases the rate will no longer be stationary, but may become oscillatory or even chaotic. These phenomena have to be ascribed to the nonlinear character of the coupled differential equations modelling the temporal behavior of the surface concentrations of the reacting species. As a consequence, these concentrations may also exhibit spatial differences, even on ana priori uniform single crystal surface, leading to spatiotemporal patterns such as propagating and standing waves as well as ‘chemical’ turbulence. Experimental evidence for these effects is presented for a particular system, the oxidation of CO on a Pt(110) surface.

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References

  1. For a recent review see: F. Razón and R.A. Schmitz, Catal. Rev. Sci. Eng. 28 (1986) 89.

    Google Scholar 

  2. G. Ertl, Adv. Catalysis 37 (1990) in press.

  3. M. Eiswirth, P. Möller, K. Wetzl, R. Imbihl and G. Ertl, J. Chem. Phys. 90 (1989) 510.

    Google Scholar 

  4. T. Engel and G. Ertl, Adv. Catalysis 28 (1979) 1.

    Google Scholar 

  5. M. Eiswirth, K. Krischer and G. Ertl, Appl. Phys. A51 (1990) 79.

    Google Scholar 

  6. T. Gritsch, D. Coulman, R.J. Behm and G. Ertl, Phys. Rev. Lett. 63 (1989) 1086.

    Google Scholar 

  7. K. Krischer, M. Eiswirth and G. Ertl, Surf. Sci. (in press);

  8. K. Krischer, thesis FU Berlin (1991).

  9. S. Jakubith, S. Nettesheim, H.H. Rotermund and G. Ertl, to be published.

  10. J.M.T. Thompson and H.B. Stewart,Nonlinear Dynamics and Chaos (Wiley, New York, 1987).

    Google Scholar 

  11. F. Takens, in:Dynamical Systems and Turbulence, eds. D.A. Rond and L.S. Young (Springer, Heidelberg, 1981) p. 336.

    Google Scholar 

  12. See e.g. O. Gurel and D. Gurel,Oscillations in Chemical Reactions (Springer, Heidelberg, 1983).

    Google Scholar 

  13. W. Engel, M. Kordesch, H.H. Rotermund, S. Kubala and A. von Oertzen, Ultramicroscopy (in press).

  14. S. Jakubith, H.H. Rotermund, W. Engel, A. von Oertzen and G. Ertl, Phys. Rev. Lett. 65 (1990) 3013.

    Google Scholar 

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  1. Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, W-1000, Berlin 33, Germany

    G. Ertl

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  1. G. Ertl
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Ertl, G. Temporal and spatial self-organisation in catalysis at single crystal surfaces. Catal Lett 9, 219–230 (1991). https://doi.org/10.1007/BF00773180

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  • DOI: https://doi.org/10.1007/BF00773180

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