Abstract
A scheme for the complete characterization of seven-membered ring conformation is described. Parameters of puckering which are calculated directly from crystallographic coordinates are used to map the conformation onto a torus in relation to the various symmetrical forms.
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Bocian, D. F., Pickett, H. M., Rounds, T. C., and Strauss, H. L. (1975)J. Am. Chem. Soc. 97, 687.
Boeyens, J. C. A. (1978)J. Crys. Mol. Struct. 8, 317.
Cremer, D., and Pople, J. A. (1975)J. Am. Chem. Soc. 97, 1354.
Flapper, W. M. J., and Romers, C. (1975)Tetrahedron 31, 1705.
Flapper, W. M. J., Verschoor, G. C., Rutten, E. W. M., and Romers, C. (1977)Acta Cryst. B 33, 5.
Graveron-Demilly, D. (1977)J. Chem. Phys. 66, 2874.
Hendrickson, J. B. (1967)J. Am. Chem. Soc. 89, 7036; 7047.
Mielczarek, I., and Rutko, F. (1976)Wiad. Chem. 6, 364.
Puckett, R. T., Sim, G. A., and Waite, M. G. (1971)J. Chem. Soc. (B),935.
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Boessenkool, I.K., Boeyens, J.C.A. Identification of the conformational type of seven-membered rings. Journal of Crystal and Molecular Structure 10, 11–18 (1980). https://doi.org/10.1007/BF01209549
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DOI: https://doi.org/10.1007/BF01209549