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Crystal and molecular structure of nitrito-bis(1,3-propanediamine) nickel(II) tetraphenylborate

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Abstract

The title compound is orthorhombic,M r =590.2,P212121 (No. 19),a=9.865(2),b=9.924(2),c=31.202(7) Å,V=3055(2) Å3,Z=4,D x =1.283 g cm−3, λ(MoK α);F(000)=1256; μ(MoK α)=6.76 cm−1, finalR=0.052 for 1441 reflections ∥I≥2.5σ(I)∥. The nitrite group is chelated via the two oxygen atoms; the two six-membered rings resulting from the coordination of the 1,3-propanediamine ligands to the nickel(II) atom are in the chair conformation. The Ni-N and Ni-O distances average 2.07(1) and 2.14(2) Å respectively. The two Ni-O distances are nearly equivalent.

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Authors and Affiliations

  1. Departament de Química Inorgánica Facultat de Química, Universitat de Barcelona, Diagonal, 647, 08028, Barcelona, Spain

    Joan Ribas, Montserrat Monfort & Carmen Diaz

  2. Departament de Cristallografia, Universitat de Barcelona, Gran Via, 645, 08007, Barcelona, Spain

    Manuel Font-Altaba & Xavier Solans

Authors
  1. Joan Ribas
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  2. Montserrat Monfort
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  3. Carmen Diaz
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  4. Manuel Font-Altaba
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  5. Xavier Solans
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Ribas, J., Monfort, M., Diaz, C. et al. Crystal and molecular structure of nitrito-bis(1,3-propanediamine) nickel(II) tetraphenylborate. Journal of Crystallographic and Spectroscopic Research 17, 303–312 (1987). https://doi.org/10.1007/BF01161429

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  • DOI: https://doi.org/10.1007/BF01161429

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