Abstract
The crystal structure of bis (NN-di(n-propyl)dithiocarbamato iron(III) iodide, FeIII(S2CN6H14)2I, has been determined by the heavy-atom method and refined toR=0.055 for 3487 reflections withI(hkl)>3σI(hkl). The crystals are triclinic,C¯1,Z=8,a=27.644(6),b=19.186(4),c=8.694(2) Å,α=87.79(1),β=88.72(1), γ=101.87(2)°. The I-Fe bond lengths are different in the two moleculesA andB in the asymmetric unit, having values of 2.642 Å (2.655) and 2.612 Å (2.634) respectively (libration-corrected values given in parentheses). The measured effective magnetic momentμ eff≈3.89 BM, independent of temperature (93-353K), suggests a spinS of 3/2 with three unpaired electrons for FeIII.
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Abbertsson, J., and Oskarsson, A. (1979)Acta Crystallogr. B,25, 1473–1476.
Butcher, R. J., and Sinn, E. (1976)J. Am. Chem. Soc. 98, 2440–2449, 5151–5168.
Cromer, D. T., and Liberman, D. (1970)J. Chem. Phys. 53, 1891–1904.
Cukauskas, E. J., Deaver, B. S., and Sinn, E. (1977)J. Chem. Phys. 67, 1257–1263.
Davis, G. R., Jarvis, J. A. J., Kilbaum, B. T., Mais, R. H. B., and Owston, P. G. (1970)J. Chem. Soc. (A) 1275–1284.
Ewald, A. H., Martin, R. L., Sinn, E., and White, A. H. (1969)Inorg. Chem. 8, 1837–1847.
Griffith, J. S. (1956)J. Inorg. Nucl. Chem. 2, 1–10.
Healy, P. C., and White, A. H. (1972a)J. Chem. Soc. Dalton Trans., 1369–1374.
Healy, P. C., and White, A. N. (1972b)J. Chem. Soc. Dalton Trans. 1163–1168.
Hoskins, B. F., and White, A. H. (1970)J. Chem. Soc. (A), 1668–1674.
International Tables for X-ray Crystallography (1962) Vol. IIIJ. Chem. Soc. Dalton Trans. (Kynock Press, Birmingham), p. 276.
Kettle, S. F. A. (1970)Coordination Compounds (Appleton-Century-Crofts, New York).
Leipoldt, J. G., and Coppens, P. (1973)Inorg. Chem. 12, 2269–2278.
Lewis, J., and Wilkins, R. G. (1960)Coordination Chemistry, Principles and Methods (Wiley-Interscience, New York).
Martin, R. L., and White, A. H. (1967)Inorg. Chem. 6, 712–721.
Mitra, S., Raston, C. L., and White, A. H. (1976)Aust. J. Chem. 29, 1899–1904.
Mitra, S., Figgis, B. M., Raston, C. L., Skeleton, B. W., and White, A. H. (1979)J. Chem. Soc. Dalton Trans., 753–758.
Moosai-Maharaj, R. C. (1976), unpublished results.
North, A. C. T., Phillips, D. C. and Matthews, F. S. (1968)Acta Crystallogr. A 24, 351–359.
Schomaker, V., and Trueblood, D. N. (1968)Acta Crystallogr. B 24, 63–76.
Sheldrick, G. M. (1976)Shelx 76 Program for Crystal Structure Determination (University of Cambridge).
Sheldrick, G. M., and Roberts, P. (1975) XANADU Geometry Program, University of Cambridge.
Wickman, H. H., and Trozzolo, A. M. (1968)Inorg. Chem. 7, 63–69.
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Abdol Abadi, B.E., Palmer, R.A. & Fitzsimmons, B.W. Crystal structure of form 1, magnetic properties and polymorphism of bis (NN-di-(n-propyl)dithiocarbamato iron (III) iodide. Journal of Crystallographic and Spectroscopic Research 18, 35–53 (1988). https://doi.org/10.1007/BF01171023
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DOI: https://doi.org/10.1007/BF01171023