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Crystal structure of chloro(dicarbonyl) bis(acetonitrile) (π-2-methallyl) molybdenum(II)

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Abstract

The title compound crystallizes in the monoclinic spacegroup P21/m with a = 6.796(9), b = 12.145(14), c = 7.749(8)Å, β = 101.86(1)°, and Z = 2. The crystal structure consists of molecules of [MoCl(CO)2(NCMe)2(η3-C3H4Me-2)] with crystallographically imposed Cs symmetry and has a pseudo-octahedral geometry, with the π-allyl group trans- to the chloro group and the two cis-carbonyl and acetonitrile groups occupying the equatorial plane.

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Authors and Affiliations

  1. Department of Chemistry, University of Reading, Whiteknights, Reading, RG6 6AD, UK

    Michael G.B. Drew & Archie W. Johans

  2. Department of Chemistry, University of Wales, Bangor, Gwynedd, LL57 2UW, UK

    Paul K. Baker & Margaret M. Meehan

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  1. Paul K. Baker
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  2. Michael G.B. Drew
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Baker, P.K., Drew, M.G., Johans, A.W. et al. Crystal structure of chloro(dicarbonyl) bis(acetonitrile) (π-2-methallyl) molybdenum(II). Journal of Chemical Crystallography 28, 839–841 (1998). https://doi.org/10.1023/A:1021836022191

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