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Crystal structures of the cobalt(III), nickel(II), copper(II), and zinc(II) complexes of 2-thio-6-picoline N-oxide

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Abstract

Structures of the following compounds have been solved: tris(2-thio-6-picoline N-oxide)cobalt(III), [Co(6MOS)3], orthorhombic, Pca21, a = 17.871(3), b = 14.061(2), c = 15.964(2) Å, V = 4011(1) Å3, Z = 8, and μ = 1.193 mm−1; bis (2-thio-6-picoline N-oxide)nickel(II), [Ni(6MOS)2], orthorhombic, Pbca, a = 15.602(8), b = 13.606(4), c = 13.348(8) Å, V = 2833(4) Å3, Z = 8, and μ = 1.655 mm−1; bis(2-thio-6-picoline N-oxide)copper(II), [Cu(6MOS)2], orthorhombic, Pbca, a = 13.914(5), b = 12.984(5), c = 15.663(6) Å, V = 2830(2) Å3, Z = 8, and μ = 1.836 mm−1; and bis(2-thio-6-picoline N-oxide)zinc(II), [Zn(6MOS)2], triclinic, P − 1, a = 7.9737(8), b = 11.7786(9), c = 7.9206(8) Å, α = 104.502(7), β = 104.495(8), γ = 93.445(8)°, V = 691.3(1) Å3, Z = 2, and μ = 2.106 mm−1. The steric effect of the methyl group in the six-position of the N-oxide ring is considered in comparing these structures to complexes of 2-thiopyridine N-oxide.

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Authors and Affiliations

  1. Department of Chemistry, Illinois State University, Normal, Illinois, 61790-4160

    Douglas X. West & Christine A. Brown

  2. Department of Chemistry, Keene State College, Keene, New Hampshire, 03431

    Jerry P. Jasinski, John M. Jasinski, Rick M. Heathwaite & David G. Fortier

  3. Department of Chemistry, Harvard University, Cambridge, Massachusetts, 02138

    Richard J. Staples

  4. Department of Chemistry, Howard University, 2400 Sixth Street N.W., Washington D.C, 20059

    Ray J. Butcher

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  1. Douglas X. West
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  2. Christine A. Brown
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  3. Jerry P. Jasinski
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  6. David G. Fortier
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West, D.X., Brown, C.A., Jasinski, J.P. et al. Crystal structures of the cobalt(III), nickel(II), copper(II), and zinc(II) complexes of 2-thio-6-picoline N-oxide. Journal of Chemical Crystallography 28, 853–860 (1998). https://doi.org/10.1023/A:1022886116342

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