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Synthesis and crystal structure of (+)-(2R,3R)-N, N′-bis-trityl-2,3-bis-aziridine

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Abstract

A new C2 symmetric bis-aziridine derivative was synthesized starting from L-(+)-tartaric acid. The molecular structure of (+)-(2R, 3R)-N, N′-bis-trityl-2,3-bis-aziridine 4, was determined by 1H, 13C NMR and elemental analysis and was confirmed by single-crystal X-ray diffraction. Crystal data for 4: C42H36N2, orthorhombic, space group: P212121, a = 12.7633(14), b = 14.5661(6), c = 17.4184(14) Å, and Z = 4.

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Authors and Affiliations

  1. Department of Organic Chemistry, NSR Center for Molecular Structure, Design and Synthesis, University of Nijmegen, Toernooiveld 1, 6525 ED, Nijmegen, The Netherlands

    P. J. J. A. Buijnsters, F. P. van der Reijden, M. C. Feiters, N. A. J. M. Sommerdijk, R. J. M. Nolte & B. Zwanenburg

  2. Department of Inorganic Chemistry, NSR Center for Molecular Structure, Design and Synthesis, University of Nijmegen, Toernooiveld 1, 6525 ED, Nijmegen, The Netherlands

    R. de Gelder

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  1. P. J. J. A. Buijnsters
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  3. M. C. Feiters
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  4. R. de Gelder
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  6. R. J. M. Nolte
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  7. B. Zwanenburg
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Buijnsters, P.J.J.A., van der Reijden, F.P., Feiters, M.C. et al. Synthesis and crystal structure of (+)-(2R,3R)-N, N′-bis-trityl-2,3-bis-aziridine. Journal of Chemical Crystallography 29, 179–183 (1999). https://doi.org/10.1023/A:1009518010352

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