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Synthesis and crystal structure of K3Sb4BO13

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Abstract

K3Sb4BO13, Mr = 823.11 g.mol−1, crystallizes in the triclinic system, space group P\(\overline 1\), Z = 2. The lattice parameters are a = 7.133(1) Å, b = 7.232(1) Å, c = 13.259(2) Å, α = 82.00 (1)°, β = 99.77(1)° and γ = 117.08(1)°, V = 598.7(2) Å3, Dx = 4.566 Mg m−3. The final R index and weighted Rw index are 0.0251 and 0.0623, respectively. The three-dimensional network of the title compound is constituted by layers (Sb3O9)n, similar to that of hexagonal bronze of Magneli. These layers are linked together, in the c direction, alternatively by edge-sharing pairs of SbO6 octahedra and BO3 triangles. This framework has interconnected tunnels, running approximately along the a and b directions, in which the K+ ions are located.

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Authors and Affiliations

  1. Faculté des Sciences de Monastir, Département de Chimie, 5000, Monastir-Tunisie

    Mohamed Mongi Ftini & Amor Haddad

  2. Faculté des Sciences de Tunis, Département de Chimie, Campus Universitaire, 1060, Tunis-Tunisie

    Tahar Jouini

Authors
  1. Mohamed Mongi Ftini
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  2. Amor Haddad
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  3. Tahar Jouini
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Ftini, M.M., Haddad, A. & Jouini, T. Synthesis and crystal structure of K3Sb4BO13. Journal of Chemical Crystallography 30, 53 (2000). https://doi.org/10.1023/A:1009598116581

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