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Crystal structure of [WI2(CO)2{P(OiPr)3}(η2-EtC2Et)]

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Abstract

[WI2(CO)2{P(OiPr)3}(η2-EtC2Et)] crystallizes in the monoclinic space group P21/n, with a = 11.101(12), b = 16.272(18), c = 14.892(17) Å, β = 93.27(1), Z = 4. The geometry can be considered to be pseudo-octahedral, with the 3-hexyne ligand occupying one site, with two iodo-groups, and the P(OiPr)3 ligand completing the equational plane of ligands, with two trans-carbonyl groups occupying the axial sites.

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Author information

Authors and Affiliations

  1. Department of Chemistry, University of Wales, Bangor, Gwynedd, LL57 2UW, Wales, UK

    Mutlaq Al-Jahdali

  2. Department of Chemistry, University of Wales, Bangor, Gwynedd, LL57 2UW, Wales, UK

    Paul K. Baker

  3. Department of Chemistry, University of Reading, Whiteknights, Reading, RG6 6AD, UK

    Michael G.B. Drew

Authors
  1. Mutlaq Al-Jahdali
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  2. Paul K. Baker
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  3. Michael G.B. Drew
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Al-Jahdali, M., Baker, P.K. & Drew, M.G. Crystal structure of [WI2(CO)2{P(OiPr)3}(η2-EtC2Et)]. Journal of Chemical Crystallography 30, 181–184 (2000). https://doi.org/10.1023/A:1009531014474

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