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Doubly-bridged binuclear complexes of oxomolybdenum(V) and oxotungsten(V) containing sexadentate ligands

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Abstract

Binuclear oxomolybdenum(V) and oxotungsten(V) complexes of the type, [M 2(O)2(μ-X)(μ-X 1)]”, where M=Mo, W;X.X 1=O, S; L=edta, pdta (n=2-), tpen, tppn (n=2+) (edta4– =ethylenediaminetetraacetate(4–), pdta=R- orR,S-propylenediaminetetraacetate(4–), tpen=N,N,N 1,N1-tetrakis(2-pyridyhnethyl)-ethylenediamine, and tppn=R- orR,S-N,N,N 1,N1-tetrakis(2-pyridylmethyl)-propylenediami ne) are reviewed with respect to their preparation, structure, spectroscopic properties, reactivities, and in particular asymmetric distortion around the bicyclo [4.1.1 ] type core and stereoselectivity related to this distortion,

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Tohoku University, Sendai 980, Aoba-ku, Japan

    Kazuo Saito

  2. Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060, Kira-ku, Japan

    Yoichi Sasaki & Ryoichi Hazama

Authors
  1. Kazuo Saito
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  2. Yoichi Sasaki
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  3. Ryoichi Hazama
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Dedicated to Professor Jiaxi Lu on the occasion of his 80th birthday and in recognition of his pioneering contributions.

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Saito, K., Sasaki, Y. & Hazama, R. Doubly-bridged binuclear complexes of oxomolybdenum(V) and oxotungsten(V) containing sexadentate ligands. J Clust Sci 6, 549–566 (1995). https://doi.org/10.1007/BF01165773

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