Abstract
The crystallization enthalpy of LiCl at 25°C in LiCl-H2O-cosolvent systems is determined calorimetrically as a function of the cosolvent content in the mixed solvent. This parameter is used for the investigation of heat phenomena accompanying the solvation of the salt in a saturated solution. The cosolvents employed include methanol, acetone, and N,N-dimethylformamide. The most pronounced change is effected by replacement of water with N,N-dimethylformamide.
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Emons, H.H., Jahn, H. & Wolf, G. Investigation of salt — Mixed solvent systems. XXXVII. Crystallization enthalpy of lithium chloride in mixed solvent systems. J Solution Chem 19, 437–446 (1990). https://doi.org/10.1007/BF00650376
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DOI: https://doi.org/10.1007/BF00650376