Abstract
The excess molar volumes V Em at atmospheric pressure and at 25, 35 and 45°C for binary mixtures of 1-nonanol, with n-heptane have been obtained over the whole mole fraction range from densities measured with a vibrating-tube densimeter. The measurements at 25°C were extended to high dilution of 1-nonanol. The V Em are sigmoid for the three temperatures, with a small maximum at low mole fractions of the alkanol. The absolute values of V Em increase with temperature from 25 to 45°C.
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Communicated in part at the 4th International Conference on Thermodynamics of Solution of Non-Electrolytes, Santiago de Compostela, Spain (1989).
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de la Fuente, I.G., Rodríguez, J.F., González, J.A. et al. Excess molar volumes of 1-nonanol withn-heptane at 25, 35 and 45°C1 . J Solution Chem 21, 425–431 (1992). https://doi.org/10.1007/BF00649696
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DOI: https://doi.org/10.1007/BF00649696