Abstract
The excess molar volumes V E m at atmospheric pressure and at 25°C for binary mixtures of diethyl carbonate with n-heptane, n-decane, n-tetradecane, 2,2,4-trimethylpentane, cyclohexane, benzene, toluene, or tetrachloromethane have been obtained over the whole mole-fraction range from densities measured with a vibrating-tube densimeter. The V E m are positive for all the systems investigated, except for the mixture with toluene which is negative. The results for V E m together with data previously published on excess molar enthalpies H E m and excess molar Gibbs energies G E m , suggest interactions between carbonate and hydrocarbons which are stronger with aromatic than with aliphatic hydrocarbons.
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Thermodynamics of binary mixtures containing organic carbonates, Part 10.
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García de la Fuente, I., González, J.A., Cobos, J.C. et al. Excess molar volumes of diethyl carbonate with hydrocarbons or tetrachloromethane at 25°C. J Solution Chem 24, 827–835 (1995). https://doi.org/10.1007/BF01131047
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DOI: https://doi.org/10.1007/BF01131047