Abstract
Electromotive-force measurements are reported for mixtures of HBr and BaBr2 in water at 25°C at constant total ionic strengths. Activity coefficients for HBr were analyzed using Pitzer's equations and Scatchard's neutral-electrolyte treatment. Both methods gave comparable results if the effects of higher-order electrostatic terms on the H+−Ba+2 interactions were included in Pitzer's treatment. Furthermore, the value of the H+−Ba+2 interaction parameter, θ(s), which should be independent of the anion, is indeed close to that for binary mixtures of these ions having chloride as common ion.
Similar content being viewed by others
References
K. H. Khoo, C. Y. Chan, and T. K. Lim,J. Solution Chem. 6, 651 (1977).
K. H. Khoo, T. K. Lim, and C. Y. Chan,J. Solution Chem. 7, 291 (1978).
K. H. Khoo, T. K. Lim, and C. Y. Chan,J. Chem. Soc. Faraday Trans. 1,74, 2037 (1978).
K. S. Pitzer and G. Mayorga,J. Phys. Chem. 77, 2300 (1973).
K. S. Pitzer,J. Solution Chem. 4, 249 (1975).
R. M. Rush and J. S. Johnson,J. Phys. Chem. 72, 767 (1968).
H. B. Hetzer, R. A. Robinson, and R. G. Bates,J. Phys. Chem. 66, 1423 (1962).
H. S. Harned, A. S. Keston, and J. G. Donelson,J. Am. Chem. Soc. 58, 989 (1936).
H. S. Harned and J. G. Donelson,J. Am. Chem. Soc. 59, 1280 (1937).
K. S. Pitzer and J. J. Kim,J. Am. Chem. Soc. 96, 5701 (1974).
K. J. Biermann and R. S. Yamasaki,J. Am. Chem. Soc. 77, 241 (1955).
R. A. Robinson and R. H. Stokes,Electrolyte Solutions, 2nd revised ed. (Butterworths, London, 1970).
K. H. Khoo, C. Y. Chan, and T. K. Lim,J. Chem. Soc. Faraday Trans. 1 74, 837 (1978).
H. S. Harned and B. B. Owen,The Physical Chemistry of Electrolytic Solutions, 3rd ed. (Reinhold, New York, 1958), p. 716.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Khoo, K.H., Lim, TK. & Chan, CY. Ionic interactions in the system HBr + BaBr2 + H2O at 25°C. J Solution Chem 8, 277–282 (1979). https://doi.org/10.1007/BF00650745
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00650745