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Atomic and molecular emission spectroscopy on an expanding argon/methane plasma

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Abstract

A supersonically expanding cascaded arc plasma in argon is analyzed axperimentally by emission spectroscopy. The thermal cascaded arc plasma is allowed to expand through a conically shaped nozzle in the arc anode into the vacuum vessel. In the nozzle monomers (C n H v ) are injected. The monomers are dissociated and ionized by the argon carrier plasma, and transported toward a substrate by means of the expansion. Emission spectroscopy is used to obtain temperatures and particle densities. By varying external parameters (e.g., arc power, gas flow rates) plasma parameters can be linked with (e.g. parameters (e.g., refractive index).

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References

  1. P. C. Zalm,Pure Appl. Chem. 57, 1253 (1985).

    Google Scholar 

  2. Cf. Invited Papers of ISPC conferences: ISPC-7 Eindhoven (1985), published inPure Appl. Chem. 57 (1985); ISPC-8 Tokyo ( 1987), published inPure Appl. Chem. 60 (1988). D. C. Schram, F. J. de Hoog, T. Ff. J. Bisschops. and G. M. W. Kroesen, Proc. SASP, Obertraun (1986), p. 181. D. C. Schram, T. H. I. Bisschops, G. M. W. Kroesen, and F. J. de Hoog,Plasma Phys. Contr. Fusion 29, 1353 (1987).

  3. G. M. W. Kroesen, Ph.D. Thesis, Eindhoven University of Technology, The Netherlands (1988).

  4. G. M. W. Kroesen, D. C. Schram, and M. J. F. van de Sande,Plasma Chem. Plasma Process. 10, 49 (1990).

    Article  Google Scholar 

  5. P. K. Bachmann, H. Lydtin, D. U. Wiechert, J. J. Bculcns, G. M. W. Krocsen. and D. C. Schram, Proc. Third International Conf. on Surface Modification Technologies, Neuchatel, Switzerland (1989).

  6. A. T. M. Wilbers, G. J. Mecusen, M. Haverlag, G. M. W. Kroesen, and D. C. Schram,Thin Solid Films 204, 59 (1991).

    Article  Google Scholar 

  7. G. M. W. Kroesen, C. J. Timmermans, and D. C. Schram,Pure Appl. Chem.,60, 795 (1988).

    Google Scholar 

  8. J. J. Bculcns, P. C. N. Crouzen, G. M. W. Kroesen, H. Vasmel, C. B. Beijer, D. C. Schram, H. J. A. Schuurmans, C. J. Timmermans, and J. Werner,J. Appl. Polym. Sci. Symp. 46 (1990).

  9. A. J. M. Buuron, J. J. Beulens, M. J. F. van de Sande, and D. C. Schram,Fusion Technol. 19, 2049 (1991).

    Google Scholar 

  10. G. M. W. Kroesen, D. C. Schram, A. T. M. Wilhers, and G. J. Mecusen,Contrib. Plasma Phys. 31, 1, 27 (1991).

    Google Scholar 

  11. M. C. M. van de Sanden, Ph.D. Thesis, Eindhoven University of Technology. The Netherlands (1991).

  12. R. van den Bercken and J. van Broekhoven, private communications, Eindhoven University of Technology, The Netherlands (1991 ).

  13. L. M. Biberman, V. S. Vorobcv, and I. T. Yakubov,Kinetics of Nonequilibrium Low- Temperature Plasmas, Plenum Press, New York (1987).

    Google Scholar 

  14. H. W. Drawin and P. Felenbok,Data for Plasmas in Local Therodynamic Equilibrium, Gauthiers Villars, Paris (1965).

    Google Scholar 

  15. G. J. Mecusen, E. A. Ershov Pavlov, R. F. G. Meulenbroeks, M. C. M. can de Sanden, and D. C. Schram,J. App. Phys. 71, 4156 (1992).

    Article  Google Scholar 

  16. W. L. Wiese, M. W. Smith, B. M. Miles, Atomic Transition Probabilities, NSRDS-NBS22, Washington (1969).

  17. J. Koulidiati, Internal Report, Eindhoven University of Technology, The Netherlands, VDF/NT (1991) pp.91–19.

  18. C. Gastineau, Internal Report, Eindhoven University of Technology, The Netherlands, VDF/NT (1991) pp 91–18.

  19. J. Koulidiati, Ph.D. Thesis, University d'Orleans, France (1991).

  20. J. Koulidiati, A. Czernikowski, J. J. Beulens, and D. C. Schram,Colloq. Phys. C5, suppl. au 18, Tonne 51, 297 (1990).

  21. H. Nassar and A. Cfernikowski,Colloq. Phys. C5, suppl. au 18, Tome 51, 289 (1990).

    Google Scholar 

  22. I. Kovacs,Rotational Structure in the Spectra of Diatomic Molecules, Adam Hilger, London (1969).

    Google Scholar 

  23. G. Herzberg,Molecular Spectra and Molecular Structure, Part I: Spectra of Diatomic Molecules, Van Nostrand, Princeton (1951).

    Google Scholar 

  24. G. Herzberg,Molecular Spectra mid Molecular Structure, Part I. Constants of Diatomic Molecules, Van Nostrand, Princeton (1979).

    Google Scholar 

  25. J. J. Beulens, Ph.D. Thesis, Eindhoven University of Technology, The Netherlands (1992).

  26. J. J. Bculcns, M. J. de Graaf and D. C. Schram, submitted toPlasma Sources Sci. Technol., 1992.

  27. M. J. de Graaf, R. P. Dahiya, J. L. Jauberteau, F. J. de Hoog, M. J. F. van de Sande, and D. C. Schram,Colloq. Phys. C5, suppl. au 18, Tonic 51 (1990).

  28. R. Bleckrode, Ph.D. Thesis, University of Amsterdam, The Netherlands (1961).

  29. J. J. A. M. van den Mullen. Ph.D. Thesis, Eindhoven University of Technology. The Netherlands (1986).

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Beulens, J.J., Gastineau, C., Guerrassimov, N. et al. Atomic and molecular emission spectroscopy on an expanding argon/methane plasma. Plasma Chem Plasma Process 14, 15–42 (1994). https://doi.org/10.1007/BF01448735

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  • DOI: https://doi.org/10.1007/BF01448735

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