Skip to main content
SpringerLink
Log in

Crystal structure and spectroscopic study of di-μ(1,1)-azido-di-μ(0,0-nitrato)tetrakis(3,5-lutidine)dicopper(II), [Cu(N3) (NO3) (3,5-lutidine)2]2

  • Published:
Structural Chemistry Aims and scope Submit manuscript

Abstract

A mixed ligand 1∶2 complex of copper(II) azide with 3,5-lutidine, namely di-μ(1,1)-azido-diμ(0,0)-nitrato)tetrakis(3,5-lutidine)dicopper(II) has been prepared and characterized by X-ray crystallographic and spectroscopic methods. The dimeric molecule, which possesses a crystallographic inversion center, contains twoμ(1,1) bridging azido ligands. Each copper(II) atom in the cyclic Cu2N2 unit is further coordinated by two oxygen atoms from twoμ(0,0-nitrato) bridges at Cu-O distances of 2.465(3) and 2.568(3) Å and two nitrogen atoms from the lutidine molecules [Cu-N=2.003(3) and 2.012(3) Å] to give a distorted tetragonal bipyramid. Both azido ligands are linear [N-N-N angle=179.0(4) and asymmetric Nα-Nβ=1.207(4) and Nβ-Nτ=1.135(5) Å]. The azido bridges produce a rather short Cu ⋯ Cu distance of 3.013(2) Å. Infrared and electronic data are presented and discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Dori, Z.; Ziolo, R. F.Chem. Rev. 1973,73, 247.

    Article  Google Scholar 

  2. Comarmond, J.; Plumere, P.; Lehn, J. M.; Agnes, Y.; Louis, R.; Weiss, R.; Kahn, O.; Morgenstern-Badarau, I.J. Am. Chem. Soc. 1984,104, 6330; Boillot, M. L.; Journaux, Y.; Bencini, A.; Gatteschi, D.; Kahn, O.Inorg. Chem. 1985,24, 263.

    Article  Google Scholar 

  3. Bkouche-Waksman, I.; Sikorav, S.; Kahn, O.J. Crystallogr. Spectrosc. Res. 1983,13, 303; Felthouse, T. R.; Hendrickson, D. N.Inorg. Chem. 1978,17, 444.

    Article  Google Scholar 

  4. Pickardt, J. Z.Naturforsch. 1982,37b, 110.

    Google Scholar 

  5. Goher, M. A. S.; Mak, T. C. W.Inorg. Chim. Acta 1985,99, 223.

    Article  Google Scholar 

  6. Goher, M. A. S.; Wang, R.-J.; Mak, T. C. W.J. Mol. Struct. 1991,243, 179.

    Article  Google Scholar 

  7. Agrell, I.; Lamnevik, S.Acta Chem. Scand. 1968,22, 2038.

    Google Scholar 

  8. Agrell, I.Acta Chem. Scand. 1967,21, 2647.

    Google Scholar 

  9. Soderquist, R.Acta Crystallogr. Sec. B 1968,24, 450.

    Article  Google Scholar 

  10. Agrell, I.Acta Chem. Scand. 1966,20, 1281.

    Google Scholar 

  11. Agrell, I.Acta Chem. Scand. 1969,23, 1667.

    Google Scholar 

  12. Goher, M. A. S.; Mak, T. C. W.Inorg. Chim. Acta. 1984,89, 119.

    Article  Google Scholar 

  13. Sikorav, S.; Bkouche-Waksman, I.; Kahn, O.Inorg. Chem. 1984,23, 490.

    Article  Google Scholar 

  14. Mak, T. C. W.; Goher, M. A. S.Inorg. Chim. Acta. 1986,115, 17.

    Article  Google Scholar 

  15. Goher, M. A. S.; Mautner, F. A. Z.Naturforsch. 1991,46b, 687.

    Google Scholar 

  16. Goher, M. A. S.; Mautner, F. A.Cryst. Res. Technol. 1992,27, 817.

    Google Scholar 

  17. Mautner, F. A.; Goher, M. A. S.Polyhedron 1992,11, 2537.

    Article  Google Scholar 

  18. Hedewy, S.; Goher, M. A. S.; Hoffmann, S. K.; Szczepaniak, L. S.;Spectrosc. Lett. 1987,20, 221.

    Google Scholar 

  19. Goher, M. A. S.; Mautner, F. A.Croat. Chim. Acta 1990,63, 559.

    Google Scholar 

  20. Walker, N.; Stuart, D.Acta Crystallogr. Sect. A 1983,39, 158.

    Article  Google Scholar 

  21. Sheldrick, G. M. SHELX-76, A Program for Crystal Structure Determination. University Chemical Laboratory, Cambridge, 1976.

    Google Scholar 

  22. Sheldrick, G. M. SHELXS-86. Universität Göttingen, Germany, 1986.

    Google Scholar 

  23. Spek, A. L. InComputational Crystallography; Sayre, D., Ed.; Clarendon Press: Oxford, 1982; p 528.

    Google Scholar 

  24. Stuart, J. M.: The X-RAY SYSTEM, version of 1976, Technical Report TR-466. University of Maryland, College Park, MD, 1976.

    Google Scholar 

  25. International Tables for X-Ray Crystallography, Vol. IV; Ibers, J. A.; Hamilton, W. C., Eds.; Kynoch Press: Birmingham, UK, 1974; pp 55, 99, 149. [Now distributed by Kluwer Academic Publishers, Dordrecht, The Netherlands.

    Google Scholar 

  26. Casagrande, O. L., Jr.; Klein, S. I.; Mauro, A. E.; Tomita, K.;Trans. Met. Chem. 1989,14, 45.

    Article  Google Scholar 

  27. Goher, M. A. S.; Mak, T. C. W.Inorg. Chim. Acta 1984,85, 117.

    Article  Google Scholar 

  28. Goher, M. A. S.; Mautner, F. A. Hoffmann, S. K. (to appear).

  29. Baily, N. A.; Fenton, D. E.; McLean, C. H.Inorg. Chim. Acta 1991,179, 1.

    Article  Google Scholar 

  30. Mautner, F. A.; Goher, M. A. S. (to appear).

  31. Chow, M.-Y.; Zhou, Z.-Y.; Mak, T. C. W.Inorg. Chem. 1992,31, 4900.

    Article  Google Scholar 

  32. Agrell, I.Acta Chem. Scand. 1971,25, 2965.

    Google Scholar 

  33. Goher, M. A. S.Acta Chim. Hung. 1990,127, 213.

    Google Scholar 

  34. Lever, A. B. P.Inorg. Chem. 1965,4, 1042.

    Article  Google Scholar 

  35. Nakamoto, K.Infrared Spectra of Inorganic and Coordination Compounds; Wiley: New York, 1978.

    Google Scholar 

  36. Fereday, R. J.J. Chem. Soc. A 1971, 3035.

  37. Tomlinson, A. A. G.; Hathaway, B. J.; Billing, D. E.; Nichols, P.J. Chem. Soc. A 1969, 65, and references therein.

  38. Goher, M. A. S.Acta Chim. Hung. 1988,125, 877.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institut für Physikalische und Theoretische Chemie, Technische Universität Graz, A-8010, Graz, Austria

    Franz A. Mautner

  2. Department of Chemistry, Faculty of Science, Alexandria University, Alexandria, Egypt

    Mohamed A. S. Goher

Authors
  1. Franz A. Mautner
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Mohamed A. S. Goher
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mautner, F.A., Goher, M.A.S. Crystal structure and spectroscopic study of di-μ(1,1)-azido-di-μ(0,0-nitrato)tetrakis(3,5-lutidine)dicopper(II), [Cu(N3) (NO3) (3,5-lutidine)2]2 . Struct Chem 5, 171–175 (1994). https://doi.org/10.1007/BF02262838

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02262838

Key words

Search

Navigation