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Heck reactions catalyzed by oxide-supported palladium – structure–activity relationships

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Abstract

The catalytic activity and selectivity of palladium supported on various metal oxides in carbon–carbon coupling reactions of aryl bromides with styrene (Heck reaction) were investigated. The activity is determined by the nature of the oxide support and the Pd dispersion (structure–activity relationships). The relation of homogeneous (leaching) and heterogeneous mechanisms is discussed.

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Authors and Affiliations

  1. Anorganisch-Chemisches Institut, Technische Universität München, Lichtenbergstrasse 4, D-85747, Garching, Germany

    M. Wagner, K. Köhler & L. Djakovitch

  2. Institut für Technische Chemie, Technische Universität München, Lichtenbergstrasse 4, D-85747, Garching, Germany

    S. Weinkauf

  3. Lehrstuhl für Technische Chemie, Ruhr-Universität Bochum, Universitätsstrasse 150, D-44780, Bochum, Germany

    V. Hagen & M. Muhler

Authors
  1. M. Wagner
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  2. K. Köhler
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  3. L. Djakovitch
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  4. S. Weinkauf
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  5. V. Hagen
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  6. M. Muhler
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Wagner, M., Köhler, K., Djakovitch, L. et al. Heck reactions catalyzed by oxide-supported palladium – structure–activity relationships. Topics in Catalysis 13, 319–326 (2000). https://doi.org/10.1023/A:1009022030636

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