Abstract
The crystal structure of 11,12-dihydroxydrim-8(9)-en-7-one was determined by X-ray diffraction. The unit cell parameters are a = 7.534(3), b = 12.192(5), c = 8.067(4) Å, β = 98.01(3) Å, space group P21, and Z = 2 for C15H24O3. The structure was solved by direct methods and refined in the anisotropic approximation to R = 0.051 and R w = 0.113. The intramolecular O-H⋯O hydrogen bond [2.892(6) Å] between the hydroxy groups closes an additional seven-membered H-ring in the molecule. In the crystal, the intermolecular O-H⋯O hydrogen bond [2.857(4) Å] between the hydroxyl group and the carbonyl oxygen atom links the molecules related by the translation along the c-axis to form infinite chains.
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Translated from Kristallografiya, Vol. 45, No. 2, 2000, pp. 289–291.
Original Russian Text Copyright © 2000 by Kravtsov, Gorinchno\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l}\), Mironov, Koltsa, Simonov, Vlad.
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Kravtsov, V.K., Gorinchnoi, E.K., Mironov, G.N. et al. Crystal and molecular structure of 11,12-dihydroxydrim-8(9)-en-7-one. Crystallogr. Rep. 45, 258–260 (2000). https://doi.org/10.1134/1.171176
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DOI: https://doi.org/10.1134/1.171176