Abstract
Reversible softening of the intramolecular A g(2) pentagonal pinch (PP) mode of a C60 single crystal in the face centered cubic phase has been studied as a function of laser power density by means of Raman scattering. The average temperature rise in the laser excitation spot has been determined using the Stokes to anti-Stokes integrated peak intensity ratio for the H g(1) phonon mode. Softening of the PP-mode was found to be due to heating of the sample resulting from laser irradiation, in good quantitative agreement with experimental results obtained for uniformly heated samples. These findings are in excellent agreement with results obtained by numerical calculations of the local temperature distribution and average temperature in the laser spot based on calculated integrated intensities of the Stokes and anti-Stokes bands of the PP-mode. These calculations were based on experimental data for the temperature dependence of phonon frequency and width, absorbance, and thermal conductivity in solid C60.
Similar content being viewed by others
References
P. H. M. van Loosdrecht, P. J. M. van Bentum, and G. Meijer, Phys. Rev. Lett. 68, 1176 (1992).
N. Chandrabhas, M. N. Shashikala, D. V. S. Muthy, A. K. Sood, and C. N. R. Rao, Chem. Phys. 197, 319 (1992).
K. P. Meletov, D. Christofilos, G. A. Kourouklis, and S. Ves, Chem. Phys. 236, 265 (1995).
Ping Zhou, Kai-An Wang, Ying Wang, P. C. Eklund, M. S. Dresselhaus, G. Dresselhaus, and R. A. Jishi, Phys. Rev. B 46, 2595 (1992).
J. Winter and H. Kuzmany, Solid State Commun. 84, 935 (1992).
A. M. Rao, P. Zhou, K.-A. Wang et al., Science 259, 955 (1993).
P.-A. Persson, U. Edlund, P. Jacobsson, D. Johnels, A. Soldatov, and B. Sundqvist, Chem. Phys. 258, 540 (1996).
D. S. Bethune, G. Meijer, W. C. Tang, H. J. Rosen, W. G. Golden, H. Seki, C. A. Brown, and M. S. de Vries, Chem. Phys. 179, 181 (1991).
Y. Hamanaka, S. Nakashima, M. Hangyo, H. Shinohara, and Y. Saito, Phys. Rev. B 48, 8510 (1993).
J. Sauvajol, F. Brocard, Z. Hricha, and A. Zahab, Phys. Rev. B 52, 14839 (1995).
P. H. M. van Loosdrecht, P. J. M. van Bentum, M. A. Verheijen, and G. Meijer, Chem. Phys. 198, 587 (1992).
P. H. M. van Loosdrecht, P. J. M. van Bentum, and G. Meijer, Chem. Phys. 205, 191 (1993).
Ping Zhou, Zheng-Hong Dong, A. M. Rao, and P. C. Eklund, Chem. Phys. 211, 337 (1993).
V. L. Broude, E. I. Rashba, and E. F. Sheka, Spectroscopy of Molecular Excitons [in Russian], Energoizdat, Moscow (1981).
R. C. Yu, N. Tea, M. B. Salamon, D. Lorents, and R. Malhotra, Phys. Rev. Lett. 68, 2050 (1992).
W. Hayes and R. Loudon, Scattering of Light by Crystals, John Wiley & Sons, New York (1978).
W. Krätschmer, K. Fostiropoulos, and D. Huffman, Chem. Phys. 170, 167 (1990).
Zheng-Hong Dong, Ping Zhou, J. M. Holden, P. C. Eklund, M. S. Dresselhaus, and G. Dresselhaus, Phys. Rev. B 48, 2862 (1993).
K. P. Meletov, V. K. Dolganov, O. V. Zharikov, I. W. Kremenskaya, and Yu. A. Ossip’yan, J. Phys. I 2, 2097 (1992).
M. Lax, J. Appl. Phys. 48, 3919 (1977).
M. Lax, Appl. Phys. Lett. 33, 786 (1978).
E. Liarokapis and Y. S. Raptis, J. Appl. Phys. 57, 5123 (1985).
O. Andersson, A. Soldatov, and B. Sundquist, Phys. Rev. B 54, 3093 (1996).
M. Patrini, F. Marabelli, G. Guizzetti, M. Manfredini, C. Castoldi, and P. Milani, in Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials, ed. by K. Kadish and R. Ruoff, The Electrochemical Society Inc., Pennington (1994), p. 632.
P. A. Heiney, J. E. Fisher, A. R. McGhie, W. J. Romanow, A. M. Denenstein, J. P. McCauley, A. B. Smith, and D. E. Cox, Phys. Rev. Lett. 66, 2911 (1991).
Author information
Authors and Affiliations
Additional information
Zh. Éksp. Teor. Fiz. 114, 1785–1794 (November 1998)
Published in English in the original Russian journal. Reproduced here with stylistic changes by the Translation Editor
Rights and permissions
About this article
Cite this article
Meletov, K.P., Liarokapis, E., Arvanitidis, J. et al. Softening of phonon modes in C60 crystals induced by laser irradiation: Thermal effects. J. Exp. Theor. Phys. 87, 967–972 (1998). https://doi.org/10.1134/1.558746
Received:
Issue Date:
DOI: https://doi.org/10.1134/1.558746