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Preparation and characterization of poly(9-hexylcarbazole-3,6-diylbutadiynylene)

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Summary

Oxidative polymerization of 3,6-diethynyl-9-hexylcarbazole with oxygen in the presence of copper complex affords soluble poly(9-hexylcarbazole-3,6-diylbutadiynylene) in good yield. Irradiation with UV-vis. light and annealing under nitrogen lead to photochemical and thermal cross-linking and insolubilization of the polymer film.

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References

  1. Newkirk AE, Hay AS, McDonald RS (1964) J Polym Sci A2: 2217; D’ilario L, Ettorre A, Ortaggi G, Sleiter G (1995) J Mater Sci 30: 4273; Bunten KA, Kakkar AK (1996) Macromolecules 29: 2885

    Google Scholar 

  2. Ogawa T (1995) Prog Polym Sci 20: 943

    Article  CAS  Google Scholar 

  3. Rutherford DR, Stille JK, Elliott CM, Reichert VR (1992) Macromolecules 25: 2294

    Article  CAS  Google Scholar 

  4. Mangel T, Eberhardt A, Scherf U, Bunz UHF, Müllen K (1995) Macromol Rapid Commun 16: 571

    Article  CAS  Google Scholar 

  5. Kwock EW, Baird, Jr. T, Miller TM (1993) Macromolecules 26: 2935; Miller TM, Kwock EW, Baird, Jr. T, Hale A (1994) Chem Mater 6: 1569

    Article  CAS  Google Scholar 

  6. Biswas M (1995) Proc Indian Natn Sci Acad 61: 179; Org BS, Keoshkerian B, Martin TI, Hamer GK (1985) Can J Chem 63: 147; Mort J, Emerald RL (1974) J Appl Phys 45: 174 and 3934

    CAS  Google Scholar 

  7. Beginn C, Grazulevicius JV, Strohriegl P, Simmerer J, Haarer D (1994) Macromol Chem Phys 195: 2353

    Article  CAS  Google Scholar 

  8. Takeuchi S, Schulz RC (1983) Makromol Chem Rapid Commun 4: 583; Takeuchi S (1986) ibid 7: 455; Fomine S, Posada I, Ogawa T (1995) Macromol Chem Phys 196: 3723; Carreon MP, Burillo G, Agabekov V, Ogawa T (1997) Polym J 29: 103; Jenkins IH, Kar AK, Lindsell WE, Murray C, Preston PN, Wang C, Wherrett BS (y1996) Macromolecules 29: 6365

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemical and Biochemical Engineering, Faculty of Engineering, Toyama University, 3190 Gofuku, 930, Toyama, Japan

    Takaki Kanbara, Satoru Ohshima & Kiyoshi Hasegawa

  2. Department of Chemistry, Faculty of Education, Toyama University, 3190 Gofuku, 930, Toyama, Japan

    Shigeya Takeuchi

Authors
  1. Takaki Kanbara
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  2. Satoru Ohshima
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  3. Kiyoshi Hasegawa
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  4. Shigeya Takeuchi
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Kanbara, T., Ohshima, S., Hasegawa, K. et al. Preparation and characterization of poly(9-hexylcarbazole-3,6-diylbutadiynylene). Polymer Bulletin 39, 453–458 (1997). https://doi.org/10.1007/s002890050172

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  • DOI: https://doi.org/10.1007/s002890050172

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