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Thermal degradation of some model compounds for polyvinylchloride

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Summary

The thermal stability of some model compounds for polyvinylchloride with different types of structural defects was studied. The determinations were carried out in thermal dynamical conditions using the conductometric detection of the evolved hydrogen chloride and thermogravimetrical methods. The kinetic parameters corresponding to the first stages of dehydrochlorination reaction were discussed comparatively. The following thermal stability order was obtained: macromodels withHT > macromodels with ClT > macromodels with ClA.

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Airinei, A., Buruiana, E.C., Robila, G. et al. Thermal degradation of some model compounds for polyvinylchloride. Polymer Bulletin 7, 465–471 (1982). https://doi.org/10.1007/BF00254372

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  • DOI: https://doi.org/10.1007/BF00254372

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