Abstract
The fundamental material properties of Pb1−xSnxTe, PbS1−xSex and Pb1−xSnxSe are reviewed. Expressions for the temperature and compositional dependences of the band parameters and dielectric constants based on recently published data are presented. As far as device technology is concerned, crystal growth techniques and diode fabrication procedures which are in use today are reviewed and compared. A comprehensive summary of laser properties like threshold current density, output power, efficiency, maximum operating temperature and tuning range of different diode structures are presented. Application related aspects such as long term stability are treated. Recent progress in laser theory is applied to explain experimentali th vs.T curves. The various laser applications are reviewed briefly. A new technique for monitoring gas concentrations using pulsed lasers and an integral method for signal processing is discussed and compared with the differential absorption, derivative spectroscopy. A long-path trace-gas monitoring system incorporating this new technique is presented.
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E.D. Hinkley: Opto-Electr.4, 69 (1972)
J.C. Hill, G.P. Montgomery, jr.: Appl. Opt.15, 748 (1976)
J.F. Butler, J.O. Sample: Cryogenics17, 661 (1977)
M. Mumma, T. Kostiuk, S. Cohen, D. Buhl, P.C. von Thuna: Nature253, 514 (1975)
B. Lehmann, M. Wahlen, R. Zumbrunn, H. Oeschger: Appl. Phys.13, 153 (1977)
R.J. Jensen, J.G. Marinuzzi, C.P. Robinson, S.D. Rockwood: Laser Focus12, 51 (May 1976)
T.C. Harman: InThe Physics of Semimetals and Narrow-Gap Semiconductors, ed. by D.L. Carter and R.T. Bate (Pergamon Press, New York 1971), p. 363
A.R. Calawa: J. Luminescence7, 477 (1973)
J.F. Butler: First European Electro-Optics Markets and Technology Conference, Sept. 13–15, Geneva 1972 (IPC Sci. & Technol. Press, London 1973, p. 99)
A.P. Shotov: Suppl. J. Jpn. Soc. Appl. Phys.42, 282 (1973)
T.C. Harman, I. Melngailis: In:Applied Solid State Sciences, Vol. 4 ed. by R. Wolf (Academic Press, New York 1974), p. 1
J. Hesse, H. Preier: InFestkörperproblem XV, ed. by H.J. Queisser (Pergamon/Vieweg, Braunschweig 1975, p. 229)
J. Hesse: Jap. J. Appl. Phys.16, Suppl. 16–1, 297 (1977)
I. Hayashi: Appl. Phys.5, 25 (1974/75)
J. Kuhl, W. Schmidt: Appl. Phys.3, 251 (1974)
A. Mooradian, T. Jaeger, P. Stokseth (eds.):Tunable Lasers and Application, Springer Series in Optical Sciences Vol. 3 (Springer, Berlin, Heidelberg, New York 1976)
J.O. Dimmock, I. Melngailis, A.J. Strauss: Phys. Rev. Lett.16, 1193 (1966)
J.N. Zemel, D. Jensen, R.B. Schoolar: Phys. Rev.140, A330 (1965)
J.R. Lowney, S.D. Senturia: J. Appl. Phys.47, 1771 (1976)
I.V. Kucherenko, Yu.A. Mityagin, L.K. Vodoplyanov, A.P. Shotov: Sov. Phys. Semicond.11, 282 (1977)
T.C. Harman, A.R. Calawa, I. Melngailis, J.O. Dimmock: Appl. Phys. Lett.14, 333 (1969)
R. Dalven: Infrared Phys.9, 141 (1969)
I.V. Kucherenko, M.S. Taktakishvili, A.P. Shotov: Sov. Phys. Semicond.10, 807 (1976)
R. Grisar: private communication
U. Schlichting: “Einfluß der Ladungsträgerkonzentration auf einige Halbleitereigenschaften des Bleiselenids”, Dissertation, TU Berlin (1970)
I.I. Zasavitskii: in “Proc. P.N. Lebedev Physics Institute”, Vol. 75, ed. by N.G. Basov, English Translation, Sov. Phys. Semicond. (Consultants Bureau, New York and London 1972)
J.F. Butler: Solid State Commun.7, 909 (1969)
A.R. Calawa, J.O. Dimmock, T.C. Harman, I. Melngailis: Phys. Rev. Lett23, 7 (1969)
G. Martinez: J. Nonmetals1, 207 (1973)
I.I. Zasavitskii, B.N. Matsonashvili, V.I. Pogodin, A.P. Shotov: Sov. Phys. Semicond8, 467 (1974)
I.I. Zasavitskii, A.I. Likhter, É.G. Pel', A.P. Shotov: Sov. Phys. Semicond.6, 1859 (1973)
J.M. Besson, J.F. Butler, A.R. Calawa, W. Paul, R.H. Rediker: Appl. Phys. Lett.7, 206 (1965)
J.F. Butler, A.R. Calawa: InPhysics of Quantum Electronics, ed. by P.L. Kelley, B. Lax, A.F. Tannenwald (McGraw Hill, New York 1966) p. 458
H. Flicker, N. Nereson: IEEE J.QE 12, 326 (1976)
M.S. Adler, C.R. Hewes, S.D. Senturia: Phys. Rev. B7, 5186 (1973)
P. Norton, P. Chia, T. Braggins, H. Levinstein: Appl. Phys. Lett.18, 158 (1971)
D.M. Gureev, I.I. Zasavitskii, B.N. Matsonashvili, A.P. Shotov: Proc. Intern. Conf. on the “Physics of Narrow-Gap Semiconductors”, Warszawa (1977), ed. by J. Raułuszkiewiez, M. Górska, E. Kaczmarek (PWN-Polish Scientific Publishers, Warszawa 1978) p. 109
W.W. Anderson: IEEE J.QE-13, 532 (1977)
Band parameters for these expressions were taken from: G. Appold, R. Grisar, G. Bauer, H. Burkhard, R. Ebert, H. Pascher, H.G. Häfele: Proc 14th Intern. Conf. Phys. Semicond., Edinburgh (1978). Int. Phys. Conf. Ser. No. 43, 1101 (1979)
R. Grisar, H. Burkhard, G. Bauer: Private communication, to be published in Solid State Commun.
G. Bauer: Proc. Intern. Conf. Application of High Magnetic Fields in Semiconductor Physics, Oxford, ed. by J.F. Ryan (1978_, p. 153.
T.C. Harman: J. Nonmetals1, 183 (1973)
J.W. Wagner, R.K. Willardson: Transactions Metallurg. Soc. AIME242, 366 (1968)
S.G. Parker, J.E. Pinnell, R.E. Johnson: J. Electr. Mat.3, 731 (1974)
S.G. Parker: J. Electr. Mat.5, 497 (1976)
T.C. Harman, J.P. McVittie: J. Electr. Mat.3, 843 (1974)
W. Lo: J. Electr. Mat.6, 31 (1977)
H. Maier, D.R. Daniel, H. Preier: J. Cryst. Growth35, 121 (1976)
D.R. Daniel, H. Maier, H. Prier: J. Cryst. Growth.38, 145 (1977)
B. Bansaragtschin, R. Link, G. Lehmann: Krist. u. Tech13, 269 (1978)
K.L.I. Kobayashi, Y. Kato, K.F. Komatsubara: Progr. Cryst. Growth Charact.1, 117 (1978)
H. Maier, D.R. Daniel, R. Herkert, J. Luck: J. Mat. Sci.13, 297 (1978)
H. Maier, D.R. Daniel: J. Electr. Mater.6, 693 (1977)
W. Lo: Appl. Phys. Lett.28, 154 (1976)
R.F. Brebrick, W.W. Scanlon: J. Chem. Phys.27, 607 (1957)
H. Pfeiffer: private communication
J.N. Walpole, R.W. Ralston, A.R. Calawa, T.C. Harman, J.P. McVittie: 4th IEEE Intern. Semicond. Laser Conf., Atlanta (1974)
E.A. Afamas'eva, N. Ibrakhimov, A.P. Shotov: Sov. Phys. Semicond.7, 765 (1973)
K. Lischka, W. Huber: J. Appl. Phys.47, 2565 (1976); Solid-State Electron.21, 1509 (1978)
B. Schlicht, R. Dornhaus, G. Nimtz, L.D. Haas, T. Jakobus: Solid-State Electron21, 1481 (1978)
T.X. Hoai, K.H. Herrmann: Phys. Status Solidi (b)83, 465 (1977)
K. Lischka, W. Huber, H. Heinrich: Solid State Commun.20, 929 (1976)
D. Kasemset, C.G. Fonstad: IEEE Intern. Semicond. Laser Conf., San Francisco, Calif. (1978); Appl. Phys. Lett. 34, 432 (1979)
L.N. Kurbatov, A.D. Britov, S.M. Karavaev: Sov. Phys. Semicond.9, 1045 (1976)
D.M. Gureev, O.I. Davarashvili, I.I. Zasavitskii, B.N. Matsonashvili, A.P. Shotov: Sov. Phys. Semicond.9, 1251 (1976)
L.N. Kurbatov, A.D. Britov, S.M. Karavaev, Yu.I. Gorina, G.A. Kalynzhnaya, P.M. Starik: Sov. J. Quantum Electron.5, 1137 (1976)
L.N. Kurbatov, A.D. Britov, S.M. Karavaev, G.A. Kalynzhnaya, M.I. Nikolaev, O.V. Pelevin, B.G. Girich, T.F. Terekhovich: Sov. J. Quantum Electron7, 236 (1977)
W. Ziegs, W. Riedel, H. Preier: To be published
J.D. Jensen, R.B. Schoolar: J. Vac. Sci. Technol.13, 920 (1976)
A.L. Hagström, A. Fahlman: Physica Scripta16, 432 (1977)
R.W. Grant, J.G. Peko, J.T. Longo, A.M. Andrews: J. Vac. Sci. Technol.13, 940 (1976)
T.S. Sun, S.P. Buchner, N.E. Byer, J.M. Chen: J. Vac. Sci. Technol.15, 1292 (1978)
I. Melngailis, T.C. Harman: InSemiconductors and Semimetals, Vol. 5, ed. by R.K. Willardson and A.C. Beer (Academic Press, New York 1970) p. 111
T.C. Harman, A.R. Calawa, I. Melngailis, J.O. Dimmock: Appl. Phys. Lett.14, 333 (1969)
K.W. Nill, F.A. Blum, A.R. Calawa, T.C. Harman: J. Nonmetals1, 211 (1973)
W. Lo, D.E. Swets: IEEE Device Research Conf., Santa Barbara, Calif. (1978)
G.A. Antcliffe, J.S. Wrobel: Appl. Phys. Lett.17, 290 (1970)
W. Lo, G.P. Montgomery, Jr., D.E. Swets: J. Appl. Phys.47, 267 (1976)
R. Grisar, A. Heime, H. Pfeiffer, H. Preier: Paper to be presented at the IEEE Device Research Conf., Boulder, Colorado, June 25–27 (1979)
K.J. Linden, K.W. Nill, J.F. Butler: IEEE J.QE-13, 720 (1977)
R. Carpenter, M.F. Hamer, W.P. Bickley, D.V. Eddolls: Infrared Phys.18, 193 (1977)
A.P. Shotov, O.I. Davarashvili: Izvestiya Akad. Nauk SSR, Neorg. Mat.13, 610 (1977)
S.H. Groves: J. Electr. Mat.6, 195 (1977)
L.R. Tomasetta, C.G. Fonstad: Appl. Phys. Lett.24, 567 (1974)
O.V. Kosogov, K.K. Dio, M.A. Maramzina, B.G. Girich, M.I. Nikolaev, O.V. Pelevin, T.F. Terekhovich: Sov. Phys. Semicond.11, 1113 (1977)
L.R. Tomasetta, C.G. Fonstad: Mater. Res. Bull.9, 799 (1974)
I. Kasai, D.W. Bassett: J. Cryst. Growth27, 215 (1974)
D.W. Bellavance, M.R. Johnson: J. Electr. Mater.5, 363 (1976)
D.K. Hohnke, H. Holloway: Appl. Phys. Lett.24, 633 (1974)
D.K. Hohnke, H. Holloway, K.F. Young, M. Huriey: Appl. Phys. Lett.29, 98 (1976)
D.L. Smith, V.Y. Pickhardt: J. Electr. Mater.5, 247 (1976)
D.L. Smith, V.Y. Pickhardt: To be published in J. Electrochem. Soc.
J.N. Walpole, S.H. Groves, T.C. Harman: IEEE Device Research Conf., Ithaca, N.Y. (1977)
J.N. Walpole, A.R. Calawa, R.W. Ralston, T.C. Harman, J.P. McVittie: Appl. Phys. Lett.23, 620 (1973)
J.N. Walpole, A.R. Calawa, T.C. Harman, S.H. Groves: Appl. Phys. Lett.28, 552 (1976)
A. Lopez-Otero: Thin Sol. Films49, 1 (1978)
I. Kasai, D.W. Bassett, J. Hornung: J. Appl. Phys.47, 3167 (1976)
G.F. McLane, K.J. Sleger: J. Electr. Mater.4, 465 (1975)
K. Duh, H. Preier: J. Mater. Sci.10, 1360 (1975)
M. Bleicher, H.-D. Wurzinger, H. Maier, H. Preier: J. Mater. Sci.12, 317 (1977)
R.B. Schoolar, J.D. Jensen, G.M. Black: Appl. Phys. Lett.31, 620 (1977)
R.B. Schoolar, J.D. Jensen: Appl. Phys. Lett.31, 536 (1977)
K.J. Linden: J. Electrochem. Soc.120, 1131 (1973)
H.R. Vydyanath: J. Appl. Phys.47, 5003 (1976)
E. Silberg, A. Zemel: Appl. Phys. Lett.31, 807 (1977)
M. Lanir, H. Levinstein: Infrared Phys.18, 259 (1978)
J.N. Walpole, A.R. Calawa, S.R. Chinn, S.H. Groves, T.C. Harman: Appl. Phys. Lett.29, 307 (1976)
L.R. Tomasetta, C.G. Fonstad: Appl. Phys. Lett.25, 440 (1974)
M. Yoshikawa, K. Shimohara, R. Ueda: Appl. Phys. Lett.31, 699 (1977)
S.H. Groves, K.W. Nill, A.J. Strauss: Appl. Phys. Lett.25, 331 (1974)
M. Yoshikawa, M. Koseto, R. Ueda: IEEE/OSA Conference on Laser and Electro-Optical Systems, San Diego, Calif. (1978)
J.N. Walpole, A.R. Calawa, S.R. Chinn, S.H. Groves, T.C. Harman: Appl. Phys. Lett.30, 524 (1977)
K.J. Sleger, G.F. McLane, H. Strom: IEEE Electron. Devices Meeting, Washington, D.C. (1974)
H. Preier, M. Bleicher, W. Riedel, H. Maier: Appl. Phys. Lett.28, 669 (1976)
H. Preier, M. Bleicher, W. Riedel, H. Maier: J. Appl. Phys.47, 5476 (1976)
H. Preier, M. Bleicher, W. Riedel, H. Pfeiffer, H. Maier: Appl. Phys.12, 277 (1977)
M. Bleicher, H.-D. Wurzinger: Private communication
W. Lo: 10th Intern. Conf. on Solid State Devices, Tokyo (1978); to be published in Jap. J. Appl. Phys. (Conf. proceedings)
J.N. Walpole, A.R. Calawa, R.W. Ralston, T.C. Harman: J. Appl. Phys.44, 2905 (1973)
R.W. Ralston, J.N. Walpole, A.R. Calawa, T.C. Harman, J.P. McVittie: J. Appl. Phys.45, 1323 (1974)
J.F. Butler, T.C. Harman: Appl. Phys. Lett.12, 347 (1968)
R.W. Ralston, I. Melngailis, A.R. Calawa, W.T. Linley: IEEE JQE-9, 350 (1973)
G.A. Antcliffe, S.G. Parker: J. Appl. Phys.44, 4145 (1973)
W. Lo: IEEE J.QE-13, 591 (1977)
J.N. Walpole, S.H. Groves, T.C. Harman: IEEE Device Research Conf., Ithaca, N.Y. (1977)
J.N. Walpole, A.R. Calawa, R.W. Ralston, T.C. Harman, J.P. McVittie: Appl. Phys. Lett.23, 620 (1973).
E.D. Hinkley, R.T. Ku, K.W. Nill, J.F. Butler: Appl. Opt.15, 1653 (1976)
K.W. Nill, F.A. Blum, A.R. Calawa, T.C. Harman: Appl. Phys. Lett.19, 79 (1971)
S.P. Chashchin, I.S. Aver'yanov, N.S. Baryshev; Sov. Phys. Semicond.4, 1538 (1971)
H. Pfeiffer: Private communication
W. Lo, D. Swets: IEEE Device Research Conf., Santa Barbara, Calif. (1978)
A. Heime: Private communication
L.R. Tomasetta, C.G. Fonstad: IEEE J.QE-11, 384 (1975)
W.W. Anderson: IEEE J.QE-13, 532 (1977)
W. Riedel, H. Preier: IEEE Device Research Conf., Ithaca, N.J. (1977). To be published
F. Galeski, A.É. Yunovich, K.H. Herrmann, H. Kostial, I. Rechenberg, P. Schäfer: Phys. Status Solidi (b)88, 675 (1978)
P.H.-H. Hsieh, C.G. Fonstad: IEEE J.QE-13, 17 (1977)
F. Galeski, I.A. Drazd, L.Ya. Lebedeva, V.P. Ten, A.E. Yunovich: Sov. Phys. Semicond.11, 327 (1977)
K.W. Nill: Laser Focus13, 32 (Feb. 1977)
W. Riedel: SPIE vol. 99, 3rd European Electro-Optics Conf. (1976), p. 17, and private communication
E.D. Hinkley, K.W. Nill, F.A. Blum:Laser Spectroscopy of Atoms and Molecules, ed. by H. Walther. Topics in Appl. Phys., Vol. 2 (Springer, Berlin, Heidelberg, New York 1976) p. 125
E.D. Hinkley, R.T. Ku, P.L. Kelley:Laser Monitorina of the Atmosphere, ed. by E.D. Hinkley. Topics in Appl. Phys., Vol. 14 (Springer, Berlin, Heidelberg, New York 1976) p. 237
A.D. Britov, S.M. Karavaev, G.A. Kalynzhnaya, A.L. Kurbatov, S.N. Maksimovskii, S.D. Sivachenko: Sov. J. Quantum Electron.7, 1138 (1977)
K.W. Nill, A.J. Strauss, F.A. Blum: Appl. Phys. Lett.22, 677 (1973)