Skip to main content
Log in

Doping properties of microcrystalline silicon prepared by mercury sensitized photochemical vapor deposition

  • Surfaces And Multilayers
  • Published:
Applied Physics A Aims and scope Submit manuscript

Abstract

Conductivity of photo-CVD microcrystalline silicon (μc-Si:H) in wide range of dopant gas concentration (10−5<PH3/SiH4, B2H6/SiH4<10−2) is investigated. As compared with a-Si:H, the conductivity of the film is improved more than two orders of magnitude by microcrystallization for a wide range of dopant concentration at a deposition temperature of as low as 150°C. This indicates the suitability of photo-CVD for low temperature processing. A conductivity minimum is found at a doping ratio of about B2H6/SiH4=1×10−5.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. M. Hanabusa: Mater. Sci. Rep. 2, 51–98 (1987)

    Google Scholar 

  2. T. Saito, S. Muramatsu, S. Shimada, M. Migitaka: Appl. Phys. Lett. 42, 678–679 (1983)

    Google Scholar 

  3. M. Okuyama, Y. Toyoda, Y. Hamakawa: Jpn. J. Appl. Phys. 23, L97-L99 (1984)

    Google Scholar 

  4. A. Yoshikawa, A. Yamaga: Jpn. J. Appl. Phys. 23, L91-L93 (1984)

    Google Scholar 

  5. S. Tsuda, H. Tarui, T. Matsuyama, T. Takahama, S. Nakayama, Y. Hishikawa, N. Nakamura, T. Fukatsu, M. Ohnishi, S. Nakano, Y. Kuwano: Jpn. J. Appl. Phys. 26, 28–32 (1987)

    Google Scholar 

  6. K. Suzuki, Y. Yukawa, H. Takao, K. Kuroiwa, Y. Tarui: Jpn. J. Appl. Phys. 25, L811-L813 (1986)

    Google Scholar 

  7. S. Usui, M. Kikuchi: J. Non-Cryst. Solids 34, 1–11 (1979)

    Google Scholar 

  8. Y. Uchida, T. Ichimura, M. Ueno, M. Ohsawa: J. Physic C 4, 265–268 (1981)

    Google Scholar 

  9. H. Okada, Y. Uchida, M. Matsumura: Jpn. J. Appl. Phys. 25, L718-L721 (1986)

    Google Scholar 

  10. K. Suzuki, K. Aota, T. Aihara, T. Suzuki, K. Kuroiwa, Y. Tarui: Jpn. J. Appl. Phys. 25, L624-L626 (1986)

    Google Scholar 

  11. S. Nishida, H. Tasaki, M. Konagai, K. Takahashi: J. Appl. Phys. 58, 1427–1431 (1985)

    Google Scholar 

  12. M. Konagai: Mat. Res. Soc. Symp. Proc. 70, 257–268 (1986)

    Google Scholar 

  13. H. Okabe: Photochemistry of small molecules (Wiley, New York 1978) p. 145

    Google Scholar 

  14. Y. Mishima, M. Hirose, Y. Osaka, Y. Ashida: J. Appl. Phys. 56, 2803–2805 (1984)

    Google Scholar 

  15. T. Inoue, T. Tanaka, M. Konagai, K. Takahashi: Appl. Phys. Lett. 44, 871–873 (1984)

    Google Scholar 

  16. A. Matsuda: J. Non-Cryst. Solids 59 & 60, 767–774 (1983)

    Google Scholar 

  17. A. Matsuda: Solid State Phys. 22, 375–382 (1987) (in Japanese)

    Google Scholar 

  18. In our experimental set up, a typical deposition rate for photo-CVD a-Si:H at 150°C is 100 Å/min while it increases to over 400 Å/min at the deposition temperature of 250°C

  19. W.E. Spear, G. Willeke, P.G. LeComber: Physica 117 & 118B, 908–913 (1983) (Part of their data (p-type side) were obtained by ion implantation)

    Google Scholar 

  20. R.A. Street: Phys. Rev. Lett. 49, 1187–1190 (1982)

    Google Scholar 

  21. K. Suzuki, K. Kuroiwa, Y. Tarui: Jpn. J. Appl. Phys. 27, 2032–2036 (1988)

    Google Scholar 

  22. M. Stutzmann, W.B. Jackson: Solid State Commun. 62, 153–157 (1987)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Suzuki, K., Kuroiwa, K., Kamisako, K. et al. Doping properties of microcrystalline silicon prepared by mercury sensitized photochemical vapor deposition. Appl. Phys. A 50, 227–231 (1990). https://doi.org/10.1007/BF00343422

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00343422

PACS

Navigation