Skip to main content
SpringerLink
Log in

Studies of the local structure in LixNi0.7Co0.3O2 (0.5≤x≤1.0) cathode materials

  • Published:
Ionics Aims and scope Submit manuscript

Abstract

Among the LixNi1−yCoyO2 system, LiNi0.7Co0.3O2 is being considered one of the best cathode materials due to its small volume cell expansion upon charge-discharge cycling. In order to study the modifications of structural and physical properties occurring in the cathode materials during charge, different LixNi0.7Co0.3O2 samples (0.5 ≥ x ≥ 1.0) were prepared by electrochemical lithium deintercalation in non-aqueous cells. During the first charge of the Li//LixNi0.7Co0.3O2 cell, the structural change in the cathode lattice was followed by both x-ray powder diffraction and FTIR spectroscopy at room temperature. A good correlation is found between XRD data and the local environment of the host lattice.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

6. References

  1. M.G.S.R. Thomas, W.I.F. David, J.B. Goodenough and P. Groves, Mat. Res. Bull.20, 1137 (1985).

    Article  CAS  Google Scholar 

  2. M. Broussely, F. Perton, P. Biensan, J.M. Bodet, J. Labat, A. Lecerf, C. Delmas, A. Rougier and J.P. Peres, J. Power Sources54, 109 (1995).

    CAS  Google Scholar 

  3. J.R. Dahn, U. von Sacken, M.W. Juskow and J. Al-Janabi, J. Electrochem. Soc.138, 2207 (1991).

    CAS  Google Scholar 

  4. C. Delmas, I. Saadoune and A. Rougier, J. Power Sources43–44, 595 (1993).

    Google Scholar 

  5. L.D. Dyer, B.S. Borie and G.P. Smith, J. Amer. Chem. Soc.76, 1499 (1954).

    CAS  Google Scholar 

  6. J.B. Goodenough, D.G. Wickham and W.J. Croft, J. Phys. Chem. Solids5, 107 (1958).

    CAS  Google Scholar 

  7. R.J. Gummow and M.M. Tackeray, Solid State Ionics53–56, 681 (1992).

    Google Scholar 

  8. C. Delmas and I. Saadoune, Solid State Ionics53–56, 370 (1992).

    Google Scholar 

  9. T. Ohzuku, A. Ueda, M. Nagayama, Y. Iwakoshi and H. Komori, Electrochim. Acta38, 1159 (1993).

    Article  CAS  Google Scholar 

  10. E. Zhecheva and R. Stoyanova, Solid State Ionics66, 143 (1993).

    Article  CAS  Google Scholar 

  11. A. Rougier, I. Saadoune, P. Gravereau, P. Willmann and C. Delmas, Solid State Ionics90, 63 (1996).

    Article  Google Scholar 

  12. C. Delmas, I. Saadoune and A. Rougier, J. Power Sources43–44, 595 (1993).

    Google Scholar 

  13. I. Saadoune and C. Delmas, J. Mater. Chem.6, 193 (1996).

    Article  CAS  Google Scholar 

  14. A. Rougier, I. Saadoune, P. Gravereau, P. Willmann and C. Delmas, Solid State Ionics90, 83 (1996).

    Article  CAS  Google Scholar 

  15. C. Julien, M. Massot, C. Perez-Vicente, E. Haro-Poniatowski, G.A. Nazri and A. Rougier, Mater. Res. Soc. Symp. Proc.496, 415 (1998).

    CAS  Google Scholar 

  16. A. Rougier, G.A. Nazri and C. Julien, Ionics3, 170 (1997).

    Article  CAS  Google Scholar 

  17. M. Nazri, M.D. Curtis, B. Yebka, G.A. Nazri and C. Julien, Extended Abstracts of the 193rd Meeting of The Electrochem. Soc., San Diego, CA (May 3–8, 1998), vol.98–1, Abstr. No. 48.

  18. J.N. Reimers and J.R. Dahn, J. Electrochem. Soc.139, 2091 (1992).

    CAS  Google Scholar 

  19. I. Saadoune, M. Menetrier, C. Delmas, J. Mater. Chem.7, 2505, (1997).

    Article  CAS  Google Scholar 

  20. R.D. Shannon and C.T. Prewitt, Acta Cryst.B 25, 925 (1969).

    Google Scholar 

  21. R.K. Moore and W.B. White, J. Am. Ceramic Soc.53, 679 (1970).

    CAS  Google Scholar 

  22. P. Tarte and J. Preudhomme, Spectrochim. Acta26A, 747 (1970).

    Google Scholar 

  23. C. Marichal, J. Hirschinger, P. Granger, M. Menetrier, A. Rougier and C. Delmas, Inorg. Chem.34, 1773 (1995).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire des Milieux Désordonnés et Hétérogènes, UMR 7603, Université Pierre et Marie Curie, 4 place Jussieu, 75252, Paris cedex 05, France

    S. Castro-García & C. Julien

Authors
  1. S. Castro-García
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. C. Julien
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to C. Julien.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Castro-García, S., Julien, C. Studies of the local structure in LixNi0.7Co0.3O2 (0.5≤x≤1.0) cathode materials. Ionics 4, 106–113 (1998). https://doi.org/10.1007/BF02375787

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02375787

Keywords

Search

Navigation