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Schwingungsberechnungen von dimeren und polymeren SbCl5NbCl5-Molekülen

Vibrational calculations of dimeric and polymericSbCl 5NbCl5 molecules

  • Anorganische, Struktur- und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

Normal coordinate analyses for a dimeric SbNbCl10 molecule, the finite chains SbNbCl11, Sb2Nb2Cl21 and Sb3Nb3Cl31 and the infinite chain (SbNbCl10)∞ are performed. The final force constants of the SbNbCl10 dimer are given along with the vibrational frequencies and their corresponding potential energy distributions. Symmetry coordinates for molecular vibrations are specified for finite chains SbNbCl11, Sb2Nb2Cl21 and Sb3Nb3Cl31 and the infinite chain (SbNbCl10)∞ and the constructed force fields were used to calculate the vibrational frequncies.

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Authors and Affiliations

  1. Anorganisch-Chemisches Institut, Technische Universität Clausthal, Paul-Ernst-Stra\e 4, D-3392, Clausthal-Zellerfeld, Bundesrepublik Deutschland

    Wolfgang Brockner

  2. Institutt for Fysikalsk Kjemi, Universitetet i Trondheim, Norges Tekniske Høgskole, Trondheim, Norwegen

    Sven J. Cyvin

Authors
  1. Wolfgang Brockner
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  2. Sven J. Cyvin
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Brockner, W., Cyvin, S.J. Schwingungsberechnungen von dimeren und polymeren SbCl5NbCl5-Molekülen. Monatshefte für Chemie 107, 1369–1378 (1976). https://doi.org/10.1007/BF01153916

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  • DOI: https://doi.org/10.1007/BF01153916

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