Summary.
The investigation of the quarternary systems EA/Mg/Li/Si (EA=Ca, Sr, Ba) led to a new Zintl compound Sr12Mg17.8Li2.2Si20 with an interesting allylic Si3 unit. The electronic configuration was analyzed with the help of quantum chemical calculations.
Similar content being viewed by others
Author information
Authors and Affiliations
Additional information
Received June 13, 1998. Accepted (revised) July 13, 1998
Rights and permissions
About this article
Cite this article
Nesper, R., Wengert, S. Sr12Mg17.8Li2.2Si20, die erste Zintl-Phase mit einer Si3-Kette. Monatshefte fuer Chemie 130, 197–202 (1999). https://doi.org/10.1007/PL00010165
Published:
Issue Date:
DOI: https://doi.org/10.1007/PL00010165