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Sr12Mg17.8Li2.2Si20, die erste Zintl-Phase mit einer Si3-Kette

Sr12Mg17.8Li2.2Si20, the First Zintl-Phase with a Si3 Chain

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Summary.

 The investigation of the quarternary systems EA/Mg/Li/Si (EA=Ca, Sr, Ba) led to a new Zintl compound Sr12Mg17.8Li2.2Si20 with an interesting allylic Si3 unit. The electronic configuration was analyzed with the help of quantum chemical calculations.

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Received June 13, 1998. Accepted (revised) July 13, 1998

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Nesper, R., Wengert, S. Sr12Mg17.8Li2.2Si20, die erste Zintl-Phase mit einer Si3-Kette. Monatshefte fuer Chemie 130, 197–202 (1999). https://doi.org/10.1007/PL00010165

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  • DOI: https://doi.org/10.1007/PL00010165

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