Abstract
The photolysis of 0.5 mole/l monochloroacetic acid in aqueous solution at 253.7 nm was studied and as products were determined: Cl− (ϕ=0.34), CH2OHCOOH (ϕ=0.19), CO2 (ϕ=0.12), CH3COOH (ϕ=0.08), HCHO (ϕ=0.004) and CH4 (ϕ=0.001). Based on these results a probable reaction mechanism is discussed to explain the rather complicated process.
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Neumann-Spallart, M., Getoff, N. Photolyse von Monochloressigsäure bei 253,7 nm in wäßriger Lösung. Monatshefte für Chemie 106, 1359–1367 (1975). https://doi.org/10.1007/BF00913610
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DOI: https://doi.org/10.1007/BF00913610