Abstract
The interaction of isotactic polypropylene with ethylene propylene diene terpolymer in their blends has been investigated by use of differential scanning calorimetry, dynamic mechanical analysis, wide- and small-angle x-ray scattering, and by investigating the nucleation and kinetics of crystallization of the iPP component under the polarization microscope. It is found, that the dispersion of the EPDM component in the iPP matrix is dependent on blend composition and is maximal at 10% EPDM content. An interface layer between the two components is formed by migration of iPP molecules into the EPDM phase. A model for this interface is proposed.
Similar content being viewed by others
References
Kolarik J, Agrawal GL, Krulis Z, Kovar J (1986) Polymer composites 7:463
Bartilla T, Kirch D, Nordmeier J, Prömper E, Strauch T, (1986) Plastverarbeiter 37:62
Speri WM, Patrick GR (1975) Polym Eng Sci 15/9:668
Hoppner D, Wendorff JH (1990) Colloid Polym Sci 268:500
Martuscelli E, Silvestre C, Bianchi L (1983) Polymer 24:1458
Wu S (1987) Polym Eng Sci 27/5:335
Fayt R, Jerome R, Teyssie Ph (1987) Polym Eng Sci 27/5:328
Frensch H, Jungnickel DJ (1989) Colloid Polymer Sci 267:16
Wenig W, Fiedel HW (1991) Makromol Chem 192:85
Ihm DJ, Ha CS, Kim SC (1988) Polymer (Korea) 12:249
Choudhary V, Varma HS, Varma IK (1987) J Thermal Analysis 32:579
Karger-Kocsis J, Kallo A, Szafner A, Bodor G, Senyyei Zs (1979) Polymer 20:37
Martuscelli E, Silvestre C, Abate G (1982) Polymer 23:229
Asresahegn M (1990) Thesis Univ. Duisburg
Fiedel HW, Wenig W (1989) Colloid Polym Sci 267:389
Helfand E, Sapse AM (1975) J Chem Phys 62:1327
Noolandi J (1984) Polymer Eng Sci 24:70
Sanchez IC (1984) Polymer Eng Sci 24:279
Van Krevelen DW, Hoftyzer PJ (1972) Properties of polymers, correlations with chemical structure. Elsevier Publ., Amsterdam, London, New York
Theocaris PS (1990) Colloid Polym Sci 268:414
Kefalas V, Theocaris PS, Kontou E (1988) Polymer Compos 9:229
Theocaris PS, Kefalas V (1991) J Appl Polym Sci 42:3059
Makaruk L, Polanska H (1981) Polym Bull 4:127
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Wenig, W., Wasiak, A. Interactions between the components in isotactic polypropylene blended with EPDM. Colloid Polym Sci 271, 824–833 (1993). https://doi.org/10.1007/BF00652764
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00652764