Skip to main content
SpringerLink
Log in

Separation of rhenium by thin-layer chromatography with polyethyleneimine cellulose in hydrochloric acid media

  • Originals
  • Published:
Chromatographia Aims and scope Submit manuscript

Summary

The thin-layer chromatographic behavior of 49 inorganic ions on polyethyleneimine (PEI) cellulose has been investigated in hydrochloric acid media (0.01–1.0 mol dm−3). The sorption on the cellulose decreases with increasing acid concentration for most of the ions, but As(III), Ti(IV) and Te(VI) do not exhibit any Rf variation with the acid concentration. The Rf spectra of TI(I), Cd(II), Pb(II) and Zn(II) have a maximum. Ag(I), Bi(III), Nb(V), Ta(V), Mo(VI) and W(VI) are retained tightly on the layer, due to either insoluble salt formation or extensive hydrolysis. The extremely low Rf values of Hg(II), Pd(II), Au(III), Ru(III) and Pt(IV) are accounted for by stability of their chlorocomplexes. Re(VII) distributes chromatographically, having moderate Rf values between 0.3 and 0.6, so that the selective separation of Re(VII) from the other ions is feasible.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. K. Oguma, Chromatographia,8, 669 (1975).

    Article  CAS  Google Scholar 

  2. R. Kuroda, T. Takahashi, K. Oguma, Bull. Chem. Soc. Jpn.,46, 815 (1964).

    Google Scholar 

  3. M. Lederer, L. Ossicini, J. Chromatogr.,13, 188 (1964).

    CAS  Google Scholar 

  4. K. Ishida, T. Saito, J. Chromatogr.,152, 191 (1971).

    Google Scholar 

  5. J. M. Tanzer, M. I. Krichevsky, B. Chassy, J. Chromatogr.,38, 526 (1968).

    Article  CAS  Google Scholar 

  6. R. A. Scott, G. P. Haight, Jr., Anal. Chem.,47, 2439 (1975).

    Article  CAS  Google Scholar 

  7. T. Ishida, T. Yamabe, J. Chromatogr.,56, 373 (1971).

    Google Scholar 

  8. G. R. Wellum, E. I. Tolpin, L. P. Andersen, R. Snesth, J. Chromatogr.,103, 153 (1975).

    Article  CAS  Google Scholar 

  9. T. Shimizu, E. Uehara, M. Ohtani, Chromatographia,21, 175 (1986).

    CAS  Google Scholar 

  10. T. Shimizu, M. Katsuno, N. Iizuka, J. Chromatogr.,106, 230 (1975).

    Article  CAS  Google Scholar 

  11. T. Shimizu, Y. Nakamura, K. Inami, Chromatographia,14, 83 (1981).

    Article  CAS  Google Scholar 

  12. K. A. Kraus, F. Nelson, Proc. Int. Conf. Peaceful Uses At. Energy (United Nations),7, 113 (1956).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Education, Gunma University, Aramaki, 371, Maebashi, Japan

    T. Shimizu & S. Abe

Authors
  1. T. Shimizu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. Abe
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shimizu, T., Abe, S. Separation of rhenium by thin-layer chromatography with polyethyleneimine cellulose in hydrochloric acid media. Chromatographia 21, 708–710 (1986). https://doi.org/10.1007/BF02313685

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02313685

Key Words

Search

Navigation