Skip to main content
SpringerLink
Log in

Prediction of retention data from stationary phase constants in gas chromatography

  • Originals
  • Published:
Chromatographia Aims and scope Submit manuscript

Summary

Specific retention volumes and retention indices for selected compounds can be predicted from different sets of stationary phase constants by multiple regression. Errors in the corresponding calculated retention times are between 5 and 15%. Intercept (A) and slope (B) values are given for 72 McReynolds stationary phases. The A value can be predicted from the retention index of benzene with a standard deviation of 9%.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. H. Abraham, G. S. Whiting, R. M. Doherty, W. J. Shuely, J. Chromatogr.518, 329 (1990)

    Google Scholar 

  2. M. H. Abraham, G. S. Whiting, R. M. Doherty, W. J. Shuely, J. Chromatogr.587, 213 (1991)

    Google Scholar 

  3. J. Li, A. J. Dallas, P. W. Carr, J. Chromatogr.517, 103 (1990)

    Google Scholar 

  4. J. Li, Y. Zang, P. W. Carr, Anal. Chem.64, 210 (1992)

    Google Scholar 

  5. L. Rohrschneider, J. Chromatogr.22, 6 (1966).

    Google Scholar 

  6. L. Rohrschneider, in: Advances in Chromatography, J. C. Giddings and R. A. Keller, eds., Vol4, 1967, M. Dekker, Inc., New York, pp. 333–363.

    Google Scholar 

  7. L. Rohrschneider, J. Chromatogr.39, 383 (1967).

    Google Scholar 

  8. W. O. McReynolds, J. Chromatogr. Sci.8, 685 (1970)

    Google Scholar 

  9. L. Rohrschneider, J. Chromatogr. Sci.8, 105 (1970)

    Google Scholar 

  10. A. Hartkopf, J. Chromatogr. Sci.10, 145 (1972)

    Google Scholar 

  11. C. F. Poole, T. O. Kollie, S. K. Poole, Chromatographia,34, 281 (1992)

    Google Scholar 

  12. W. O. McReynolds, Gas Chromatographic Retention Data, Preston Technical Abstracts Co., Evanston, Ill., 1966

    Google Scholar 

  13. L. S. Ettre, K. Billeb, J. Chromatogr.30, 1 (1967)

    Google Scholar 

  14. L. Rohrschneider, J. Chromatogr.17, 1 (1965)

    Google Scholar 

  15. L. Rohrschneider, J. Gas Chromatography6, 5 (1968)

    Google Scholar 

  16. L. Rohrschneider, Zeitschrift für anal. Chemie,236, 149 (1968)

    Google Scholar 

  17. L. Rohrschneider, Fortschr. Chem. Forsch.11 (1), 149 (1968).

    Google Scholar 

  18. R. W. Taft, M. H. Abraham, R. M. Doherty, M. J. Kamlet, J. Am. Soc.,107, 3105 (1985)

    Google Scholar 

  19. V. Tekler, J. M. Takács, J. Chromatogr.202, 179 (1980)

    Google Scholar 

  20. R. V. Golovnya, B. M. Polanuer, J. Chromatogr.517, 51 (1992)

    Google Scholar 

  21. L. S. Ettre, private communication

  22. E. Fernandez-Sanchez, J. A. Garcia-Dominguez, V. Mendez, J. M. Santuiste, E. Pertierra-Rimada, J. Chromatogr.402, 318 (1987).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Anorganisch-Chemisches Institut der Westfälischen Wilhelms Universität, Wilhelm Klemm Straße 8, D-48149, Münster, Germany

    L. Rohrschneider

Authors
  1. L. Rohrschneider
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rohrschneider, L. Prediction of retention data from stationary phase constants in gas chromatography. Chromatographia 37, 250–258 (1993). https://doi.org/10.1007/BF02278629

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02278629

Key Words

Search

Navigation