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Photoelectron dynamics of the cooper minimum in free molecules

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Zeitschrift für Physik D Atoms, Molecules and Clusters

Abstract

The general properties of the Cooper minimum in molecules are reviewed. Experimental results from synchrotron radiation together with theoretical calculations are presented on both the partial cross sections and angular distribution parameters, β. A detailed examination of HCl is used as an example. Previously unpublished results on CCl n H4−n , CCl n F4−n , ethylene dichloride, I2 and ICl are included. The Cooper minimum is largely discussed as a perturbation from atomic behavior, and is examined as a function of atomic number. The Cooper minimum is also examined as a function of chemical environment. Finally, needs for future research are briefly described.

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Authors and Affiliations

  1. Chemistry Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee, USA

    T. A. Carlson, M. O. Krause, W. A. Svensson & P. Gerard

  2. Royal Institute of Technology, Fysik I, Stockholm, Sweden

    W. A. Svensson & T. A. Whitley

  3. Department of Chemistry, University of Tennessee, Knoxville, Tennessee, USA

    F. A. Grimm & T. A. Whitley

  4. Eastman Chemistry Division Research Laboratory, Kingsport, TN

    B. P. Pullen

Authors
  1. T. A. Carlson
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  2. M. O. Krause
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  3. W. A. Svensson
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  4. P. Gerard
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  5. F. A. Grimm
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  6. T. A. Whitley
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  7. B. P. Pullen
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Additional information

Research sponsored by the Division of Chemical Sciences, Office of Basic Energy Sciences, U.S. Department of Energy under contract DE-AC05-840R21400 with the Martin Marietta Energy Systems, Inc

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Carlson, T.A., Krause, M.O., Svensson, W.A. et al. Photoelectron dynamics of the cooper minimum in free molecules. Z Phys D - Atoms, Molecules and Clusters 2, 309–318 (1986). https://doi.org/10.1007/BF01426235

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  • DOI: https://doi.org/10.1007/BF01426235

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