Abstract
Isotope shift (IS) and hyperfine structure (hfs) measurements have been performed on seven lines of the platinum I spectrum with interference as well as laser fluorescence spectroscopy. In the latter case a frequency-doubled single-mode cw dye laser was applied. The IS of190Pt with a natural abundance of only 0.01% was determined to beδν 190, 192=−38.65(8) mK in theλ306.47 nm transition. The IS parameters and the effective hfs integrals in the configuration (5d+6s)10 were determined in intermediate coupling by a least squares fit of the IS and hfs data with eigenvectors obtained from the platinum fine structure (fs). The results are compared with theoretical values and yield improvedδ〈r 2〉 data.
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Dedicated to Professor Siegfried Penselin on the occasion of his 60th birthday
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Neu, W., Passler, G., Sawatzky, G. et al. Isotope shift and hyperfine structure of stable platinum isotopes. Z Phys D - Atoms, Molecules and Clusters 7, 193–201 (1987). https://doi.org/10.1007/BF01384588
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DOI: https://doi.org/10.1007/BF01384588