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[(Tricarbonylmanganese)cylclopentadienyl] (triphenylphosphine)gold

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    [(Tricarbonylmanganese) cyclopentadienyl](triphenylphosphine)gold has been synthesized.

  2. 2.

    In the reaction with hydrochloric, hydroiodic, and hydrocyanic acids [(tricarbonylmanganese)cyclopentadienyl] (triphenylphosphine)gold forms tricarbonylcyclopentadienylmanganese and complexes of univalent gold salts with triphenylphosphine.

  3. 3.

    In the reaction of chlorine and bromine with [(triearbonylmanganese)cyclopentadienyl] (triphenylphosphine) gold the corresponding halogen derivatives of tricarbonylcyclopentadienylmanganese are formed, and ([bicyclopentadienyl]diyl]bis[tricarbonylmanganese], and complexes of univalent gold halides with triphenylphosphine.

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Literature cited

  1. A. N. Nesmeyanov, É. G. Perevalova, D. A. Lemenovskii, A. N. Kosina, and K. I. Grandberg, Izv. Akad. Nauk SSSR, Ser. Khim.,1969, 2030.

  2. A. N. Nesmeyanov, K. N. Anisimov, N. E. Kolobova, and Yu. V. Makarov, Izv. Akad. Nauk SSSE, Ser. Khim.,1968, 686.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    A. N. Nesmeyanov, K. I. Grandberg, T. V. Baukova, A. N. Kosina & É. G. Perevalova

Authors
  1. A. N. Nesmeyanov
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  2. K. I. Grandberg
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  3. T. V. Baukova
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  4. A. N. Kosina
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  5. É. G. Perevalova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2032–2035, September, 1969.

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Nesmeyanov, A.N., Grandberg, K.I., Baukova, T.V. et al. [(Tricarbonylmanganese)cylclopentadienyl] (triphenylphosphine)gold. Russ Chem Bull 18, 1879–1881 (1969). https://doi.org/10.1007/BF00905829

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  • DOI: https://doi.org/10.1007/BF00905829

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