Conclusions
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1.
An analysis of the kinetics of the reaction of ozone with phosphites shows that the steps of formation of a relatively stable product (RO)3PO3 is preceded by the formation of an intermediate unstable complex.
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2.
A method was developed for determining the rate constants of the primary step of the reactions of phosphites with ozone, and the rate constants were determined for 14 phosphites.
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3.
An empirical equation relating the induction constant of the substituents to the reactivity of phosphites with respect to ozone was found.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 769–774, April, 1975.
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Kurbatov, V.A., Razumovskii, S.D., Pobedimskii, D.G. et al. Rate constants and mechanism of the reaction of phosphites with ozone in carbon tetrachloride. Russ Chem Bull 24, 692–696 (1975). https://doi.org/10.1007/BF00920675
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DOI: https://doi.org/10.1007/BF00920675