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Reaction of organonickel σ complexes with p-tolyl isocyanide

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

p-Tolyl isocyanide reacts with the cymantrenyl, phenyl, and mesityl complexes of nickel to give the products of inserting the isocyanide at the Ni-C σ bond and the simultaneous displacement of the triphenyl-phosphine ligand.

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Literature cited

  1. A. N. Nesmeyanov, É. G. Perevalova, L. I. Khomik, and L. I. Leont'eva, Dokl. Akad. Nauk SSSR,209, 869 (1973).

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  2. A. N. Nesmeyanov, É. G. Perevalova, L. I. Leont'eva, and L. I. Khomik, Izv. Akad. Nauk SSSR, Ser. Khim., 938 (1974).

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    A. N. Nesmeyanov, L. I. Leont'eva & L. I. Khomik

Authors
  1. A. N. Nesmeyanov
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  2. L. I. Leont'eva
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  3. L. I. Khomik
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1656–1658, July, 1976.

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Nesmeyanov, A.N., Leont'eva, L.I. & Khomik, L.I. Reaction of organonickel σ complexes with p-tolyl isocyanide. Russ Chem Bull 25, 1571–1572 (1976). https://doi.org/10.1007/BF00920852

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  • DOI: https://doi.org/10.1007/BF00920852

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