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Reactions of the ketone group in σ-ferrocenoyl methyl(π-cyclopentadienyl)dicarbonyliron

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Reaction of σ-ferrocenoylmethyl-(π)-cyclopentadienyl)dicarbonyliron with HBF4 and triethyloxonium fluoroborate gives carboxonium salts of the type [C5H5(CO)2FeCH2C(OR)C5H4FeC5H5]+BF −4 , where R=H and C2H5, and reaction with iodine in ether gives a ketone-group complex with iodine.

  2. 2.

    The reactions of the ethoxycarbonium salt [C5H5(CO)2FeCH2C(OC2H5)C5H4FeC5H5]+BF −4 -with Nal, NaOCOCF3, and PPh3 proceed with cleavage of the Fe-Cσ bond, while its reaction with NaBH4 proceeds without cleavage of this bond, while its reaction with NaBH4 proceeds without cleavage of this bond but with formation of C5H5(CO)2FeCH2CH(OC2H5)C5H4FeC5H5.

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Literature cited

  1. A. N. Nesmeyanov, É. G. Perevalova, L. I. Leont'eva, and O. V. Grigor'eva, Izv. Akad. Nauk SSSR, Ser. Khim., 1171 (1976).

  2. A. N. Nesmeyanov, É. G. Perevalova, and L. I. Leont'eva, Izv. Akad. Nauk SSSR, Ser. Khim., 2582 (1977).

  3. A. N. Nesmeyanov, É. G. Perevalova, L. I. Leont'eva, S. A. Eremin, and O. V. Grigor'eva, Izv. Akad. Nauk SSSR, Ser. Khim., 2645 (1974).

  4. A. N. Nesmeyanov, É. G. Perevalova, L. I. Leont'eva, S. A. Eremin, and E. A. Zhdanova, Izv. Akad. Nauk SSSR, Ser. Khim., 2557 (1977).

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    A. N. Nesmeyanov, É. G. Perevalova, L. I. Leont'eva & S. A. Eremin

Authors
  1. A. N. Nesmeyanov
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  2. É. G. Perevalova
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  3. L. I. Leont'eva
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  4. S. A. Eremin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2121–2124, September, 1978.

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Nesmeyanov, A.N., Perevalova, É.G., Leont'eva, L.I. et al. Reactions of the ketone group in σ-ferrocenoyl methyl(π-cyclopentadienyl)dicarbonyliron. Russ Chem Bull 27, 1873–1876 (1978). https://doi.org/10.1007/BF00929242

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  • DOI: https://doi.org/10.1007/BF00929242

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