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Atomic hydrogen in γ-irradiated hydroxides of alkaline-earth elements

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We have detected for the first time stabilization of atomic hydrogen inγ-irradiated polycrystalline alkaline-earth element hydroxides.

  2. 2.

    Depending on the degree of dehydroxylation, several types of hydrogen atoms may be stabilized in the hydroxides, these hydrogen atoms having different radiospectroscopic parameters.

  3. 3.

    In the magnesium-calcium-strontium-barium hydroxide series, a regular decrease has been found in the hfi constants for H atoms with the cations in the immediate surroundings. A direct proportionality has been found between the parameters ΔA/A0 and the polarizability of the cation.

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Authors and Affiliations

  1. Institute of Physical Chemistry, Academy of Sciences of the USSR, Moscow

    V. I. Spitsyn, T. K. Yurik & L. I. Barsova

Authors
  1. V. I. Spitsyn
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  2. T. K. Yurik
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  3. L. I. Barsova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 762–768, April, 1982.

The authors wish to thank G. V. Ionova and B. G. Ershov for useful discussions of these results.

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Spitsyn, V.I., Yurik, T.K. & Barsova, L.I. Atomic hydrogen in γ-irradiated hydroxides of alkaline-earth elements. Russ Chem Bull 31, 672–677 (1982). https://doi.org/10.1007/BF00949995

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  • DOI: https://doi.org/10.1007/BF00949995

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