Conclusion
A method has been proposed for the synthesis of carboranyl four-and five-membered metallocycles containing carbon, palladium, boron and phosphorus atoms based on the exchange of cyclopalladized ligands between o-palladized N,N-diraethylbenzylamine and diphenylphosphino or diphenylphosphinomethyl derivatives of o-carborane.
Literature cited
A. D. Ryabov and A. K. Yatsimirskii (Yatsimirsky), Inorg. Chem.,23, 899 (1984).
A. D. Ryabov and G. M. Kazankov, J. Organomet. Chem.,268, 85 (1984).
K. Hiraki, Y. Fuchita, and T. Uchiyama, Inorg. Chim. Acta,69, 187 (1983).
W. B. Jennings, Chem. Rev.,75, 307 (1975).
V. N. Kalinin, A. V. Usatov, and L. I. Zakharkin, J. Organomet. Chem.,254, 127 (1983).
V. N. Kalinin, A. V. Usatov, and L. I. Zakharkin, Izv. Akad. Nauk SSSR, Ser. Khim., 1646 (1984).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2790–2793, December, 1986.
Rights and permissions
About this article
Cite this article
Ryabov, A.D., Usatov, A.V., Kalinin, V.N. et al. The exchange of cyclopalladized ligands as a pathway to Pd-P(C)n-B carboranyl metallocycles (n=1, 2). Russ Chem Bull 35, 2559–2562 (1986). https://doi.org/10.1007/BF01474223
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01474223