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Structure and catalytic activity of metal complexes on carriers 3. Rhodium complexes on modified polymers and their catalytic properties in the reduction of nitrobenzene by chemically bound hydrogen

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

Heterogenized catalysts based on rhodium complexes attached to polymers modified by the groups 3(5)-methylpyrazole, imidazole and benzimidazole have been synthesized. The process of their formation has been investigated by IR, UV, and EPR spectroscopy. Results have been obtained for the catalytic activity of the complexes in the hydrogenation of nitrobenzene by hydrogen transfer from propan-2-ol and NaBH4.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. F. Dovganyuk, V. Z. Sharf, V. K. Belyaeva, I. N. Marov, Zh. L. Dykh, L. I. Lafer & V. I. Yakerson

  2. V. I. Vernadskii Institute of Geochemistry and Analytical Chemistry, Academy of Sciences of the USSR, Moscow

    V. F. Dovganyuk, V. Z. Sharf, V. K. Belyaeva, I. N. Marov, Zh. L. Dykh, L. I. Lafer & V. I. Yakerson

Authors
  1. V. F. Dovganyuk
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  2. V. Z. Sharf
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  3. V. K. Belyaeva
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  4. I. N. Marov
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  5. Zh. L. Dykh
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  6. L. I. Lafer
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  7. V. I. Yakerson
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, pp. 268–273, February, 1990.

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Dovganyuk, V.F., Sharf, V.Z., Belyaeva, V.K. et al. Structure and catalytic activity of metal complexes on carriers 3. Rhodium complexes on modified polymers and their catalytic properties in the reduction of nitrobenzene by chemically bound hydrogen. Russ Chem Bull 39, 217–221 (1990). https://doi.org/10.1007/BF00960640

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  • DOI: https://doi.org/10.1007/BF00960640

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