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Thermodynamic parameters of adsorption of adamantane and its derivatives on graphitized thermal carbon black

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Abstract

The adsorption equilibrium constants for adamantane, 1-fluoro-, 1-chloro-, 1,3-difluoro-, 1,3-dichloro-, 1,3-dibromo-, and 1-hydroxyadamantane, and methyl 1-adamantyl ketone were determined by gas chromatography. The results were compared with molecular statistical calculations based on the known atomic-atomic potentials of the interaction of atoms of the sorbate molecule with the C atom of graphitized thermal carbon black (GTCB). The experimental adsorption heats exceed the calculated values by 3-10 kJ mol-1. The reasons for this divergence are discussed. The changes in the adsorption entropy show that the molecules of the studied compounds form a layer of the ideal dimeric gas on the GTCB surface upon adsorption.

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Authors and Affiliations

  1. Samara State University, 1 ul. Akad. Pavlova, 443011, Samara, Russian Federation

    S. Yu. Kudryashov, L. A. Onuchak & A. V. Voronkov

  2. Institute of Physical Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117915, Moscow, Russian Federation

    A. K. Buryak

  3. Samara State Technical University, 141 ul. Galaktionovskaya, 443010, Samara, Russian Federation

    I. K. Moiseev

Authors
  1. S. Yu. Kudryashov
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  2. L. A. Onuchak
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  3. A. V. Voronkov
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  4. A. K. Buryak
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  5. I. K. Moiseev
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Kudryashov, S.Y., Onuchak, L.A., Voronkov, A.V. et al. Thermodynamic parameters of adsorption of adamantane and its derivatives on graphitized thermal carbon black. Russian Chemical Bulletin 49, 1988–1992 (2000). https://doi.org/10.1023/A:1009511622918

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