Abbreviations
- A :
-
anode area
- C s :
-
saturation solubility of copper phosphate (as Cu2+) in H3PO4
- d :
-
disc diameter
- D :
-
diffusivity of copper ions
- F :
-
Faraday's constant
- g :
-
acceleration due to gravity
- I L :
-
limiting current
- K :
-
mass transfer coefficient
- z :
-
number of electrons involved in the reaction
- Gr :
-
Grashof number,gd 3(ρ i −ρ b)/v 2av ρ i
- Sc :
-
Schmidt numberv av/D
- Sh :
-
Sherwood number,Kd/D
- ρ i :
-
density at the interface between the anode and the solution
- ρ b :
-
bulk solution density
- v ab :
-
average kinematic viscosity
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Nirdosh, I., Sedahmed, G.H. A mass transfer study of the electropolishing of vertical discs under free convection. J Appl Electrochem 21, 651–653 (1991). https://doi.org/10.1007/BF01024856
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DOI: https://doi.org/10.1007/BF01024856