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Mössbauer study on characterization of Co[Fe(CN)5NH3 \(\cdot x \)H2O

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Abstract

The electronic states of Fe atoms in Co[Fe(CN)5NH3 \(\cdot x \)H2O were studied by means of 57Fe Mössbauer spectroscopy. The Mössbauer spectra of Co[Fe(CN)5NH3 \(\cdot \)6H2O show the coexistence of mixed valences for the Fe atoms and a magnetic relaxation at 4 K. When water molecules were removed, electron transfer from Co to Fe occurred.

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Authors
  1. Y. Einaga
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  2. Z.‐Z. Gu
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  3. Y. Kobayashi
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  4. O. Sato
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  5. T. Iyoda
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  6. F. Ambe
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  7. K. Hashimoto
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  8. A. Fujishima
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Einaga, Y., Gu, Z., Kobayashi, Y. et al. Mössbauer study on characterization of Co[Fe(CN)5NH3 \(\cdot x \)H2O. Hyperfine Interactions 116, 159–166 (1998). https://doi.org/10.1023/A:1012698016696

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  • DOI: https://doi.org/10.1023/A:1012698016696

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