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Mössbauer kinetics of formation of goethite in the basic medium: Effect of the particle size of ferrous hydroxide

  • Catalysys, Corrosion and Surface Phenomena
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Abstract

The formation of goethite in the basic medium is simulated by stirring, in the presence of air, a mixture of FeSO4.7H2O and NaOH in the 1∶5 ratio at different initial concentration C of ferrous ions. The initial oxidation product is ferrous hydroxide and its further oxidation leads mainly to goethite through active α′-FeOOH. The kinetics of the process is studied from Mössbauer spectra.

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Authors and Affiliations

  1. Laboratoire CNRS Maurice Letort UP 6851, Groupe de Spectrométrie Mössbauer Département Sciences des Matériaux, Université de Nancy 1, ESSTIN, Parc R. Bentz, F 54500, Vandoeuvre-Nancy, France

    A. A. Olowe & J. -M. R. Génin

  2. Laboratoire CNRS Maurice Letort UP 6851, Groupe de Spectrométrie Mössbauer Département Sciences des Matériaux, Université de Nancy 1, ESSTIN, Parc R. Bentz, F 54500, Vandoeuvre-Nancy, France

    A. A. Olowe & J. -M. R. Génin

Authors
  1. A. A. Olowe
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  2. J. -M. R. Génin
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Olowe, A.A., Génin, J.M.R. Mössbauer kinetics of formation of goethite in the basic medium: Effect of the particle size of ferrous hydroxide. Hyperfine Interact 69, 823–826 (1992). https://doi.org/10.1007/BF02401953

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  • DOI: https://doi.org/10.1007/BF02401953

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