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Mössbauer effect study and crystallographic structure of chlorinated green rust one compounds

  • Catalysys, Corrosion and Surface Phenomena
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Abstract

Mössbauer spectra of green rust one run at 78 and 4.4 K exhibit two ferrous and one ferric sites in the 2/1/1 intensity ratio. Chemical formula is set at 3Fe(OH)2, Fe(OH)2Cl, nH2O. By replacing Fe2+ with Ni2+ ions, the compound is stabilized and the structure is determined on a ABiBCiCai stacking sequence. Space group is P3121 with an hexagonal unit cell of parameters a=6.17 and c=23.5 A0.

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Refait, P., Rézel, D., Olowe, A.A. et al. Mössbauer effect study and crystallographic structure of chlorinated green rust one compounds. Hyperfine Interact 69, 839–842 (1992). https://doi.org/10.1007/BF02401957

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