Abstract
Mössbauer spectra of green rust one run at 78 and 4.4 K exhibit two ferrous and one ferric sites in the 2/1/1 intensity ratio. Chemical formula is set at 3Fe(OH)2, Fe(OH)2Cl, nH2O. By replacing Fe2+ with Ni2+ ions, the compound is stabilized and the structure is determined on a ABiBCiCai stacking sequence. Space group is P3121 with an hexagonal unit cell of parameters a=6.17 and c=23.5 A0.
Similar content being viewed by others
References
D. Rezel, Ph. Bauer and J.M.R. Génin, Hyp. Interactions 42 (1988) 1075–78.
Ph. Refait and J.M.R. Genin, this issue.
J.M.R. Génin, D. Rézel, Ph. Bauer, A.A. Olowe and A. Béral, Electrochem. Meth. in Corr. Res., Mat. Sci. Forum, 8 (1986) 477.
J.D. Bernal, D.R. Dasgupta and A.L. Mackay, Clay Min. Bull., 4, 21 (1959) 15–30.
L. Ingram and H.F.W. Taylor, Min. Mag., 36 (1967) 465.
R. Allmann, Acta Cryst. B24 (1968) 972.
R. Allmann, Neus Jahrb. Min., Monatsch (1969) 552.
P.P. Stampf, Corros. Sci. 9 (1969) 185.
R.M. Taylor, Clay Min. Bull. 15 (1980) 369.
E. Murad and R.M. Taylor, Clay Min. Bull. 19 (1984) 77.
K.J. Martin and T.J. Pinnavaia, J. Am. Chem. Soc. 108 (1986) 541.
R. Schöllhorn and B. Otto, J. Chem. Soc. (1980) 1222.
A. De Roy, J.P. Besse and P. Bondot, Mat. Res. Bull. 20 (1985) 1091.
H.P. Boehm, J. Steinle and C. Vieweger, Angew Chem. Int. editor, 16 n04 (1977) 265.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Refait, P., Rézel, D., Olowe, A.A. et al. Mössbauer effect study and crystallographic structure of chlorinated green rust one compounds. Hyperfine Interact 69, 839–842 (1992). https://doi.org/10.1007/BF02401957
Issue Date:
DOI: https://doi.org/10.1007/BF02401957