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129I Mössbauer spectroscopic study of metallocene-iodine adducts

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Abstract

A129I Mössbauer spectroscopic study of iodine adducts of [2]ferrocenophane, biruthenocene, and osmocene is reported. The spectra show the existence of iodine bonded to the central metals of metallocenes in addition to triiodide anions. The valence state of iron in the [2]ferrocenophane-iodine adduct is the same as those of ruthenium and osmium in their adducts.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Hiroshima University, Kagamiyama, 724, Higashi-Hiroshima, Japan

    Satoru Nakashima & Hiroshi Sakai

  2. Department of Chemistry, College of Arts and Sciences, The University of Tokyo, Komaba, Meguro, 153, Tokyo, Japan

    Masanobu Watanabe

  3. Research Reactor Institute, Kyoto University, Kumatori, Sennan, 590-04, Osaka, Japan

    Yutaka Maeda

Authors
  1. Satoru Nakashima
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  2. Hiroshi Sakai
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  3. Masanobu Watanabe
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  4. Yutaka Maeda
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Nakashima, S., Sakai, H., Watanabe, M. et al. 129I Mössbauer spectroscopic study of metallocene-iodine adducts. Hyperfine Interact 84, 545–549 (1994). https://doi.org/10.1007/BF02060707

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  • DOI: https://doi.org/10.1007/BF02060707

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