Abstract
In order to monitor the peculiar temperature dependence of the magnetization of the compounds YCo4B and CeCo4B from an atomistic point of view, samples doped with 1%57Fe were studied by Mössbauer spectroscopy. From the two Co-sites present in this structure (2c, 6i), only the latter were found to be equipped by Fe. In the case of the Y-compound, the change of direction of the easy axis of magnetization could be confirmed. The broad maximum observed for the magnetization of the Ce-compound is not reflected by the57Fe hyperfine field.
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Wiesinger, G., Pavlovec, R., Hong, N.M. et al. Local magnetic order in57Fe doped Y(Ce)Co4B. Hyperfine Interact 93, 1531–1536 (1994). https://doi.org/10.1007/BF02072904
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DOI: https://doi.org/10.1007/BF02072904